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CBSE

Subject

Chemistry
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NEET Chemistry : Aldehydes, Ketones and Carboxylic Acids

Multiple Choice Questions

31.

A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin which on hydrolysis forms a racemic mixture of alpha -hydroxy acid. The carbonyl compound is: 

  • CH3-CH2-CH2COCH3

  • (CH3)2C=O

  • CH3CH2CHO

  • CH3CH2CHO



32.

Of the following, which is the product formed when cyclohexanone undergoes aldol condensation followed by heating?



33.

Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam and conc. HCl is Called:

  • Clemmensen reduction

  • Cope reduction

  • Dow reduction

  • Dow reduction



34.

Self-condensation of two moles of ethyl acetate in presence of sodium ethoxide yields

  • ethyl butyrate

  • acetoacetic ester

  • methyl acetoacetate

  • methyl acetoacetate



35.

Which of the following represents the correct order of the acidity in the given compounds?

  • H3CCOOH > BrCH2COOH > ClCH2COOH > FCH2COOH

  • FCH2COOH > CH3COOH >BrCH2COOH > ClCH2COOH

  • BrCH2COOH > ClCH2COOH > FCH2COOH >CH3COOH

  • BrCH2COOH > ClCH2COOH > FCH2COOH >CH3COOH



36.

Which of the compounds with molecular formula C5H10 yields acetone on ozonolysis?

  • 2-methyl-2- butene

  • 3- methyl -1-butene

  • cyclopentane

  • cyclopentane



37.

In a set of reactions, propionic acid yielded a compound D.

CH subscript 3 CH subscript 2 COOH space rightwards arrow with SOCl subscript 2 on top space straight B space rightwards arrow with NH subscript 3 on top space straight C space rightwards arrow from Br subscript 2 to KOH of space straight D
The structure of D would be:

  • CH3CH2CH2NH2

  • CH3CH2CONH2

  • CH3CH2NHCH3

  • CH3CH2NHCH3



38.

The product formed in aldol condensation is:

  • a beta-hydroxy acid

  • a beta -hydroxy aldehyde or ketone

  • an alpha -hydroxy aldehyde or ketone

  • an alpha -hydroxy aldehyde or ketone



39.

A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin which on hydrolysis forms a racemic mixture of alpha-hydroxy acid. The carbonyl compound is:

  • acetaldehyde

  • acetone

  • diethyl ketone

  • diethyl ketone



40.

Which one of the following on treatment with 50% aqueous sodium hydroxide yields the corresponding alcohol and acid? 

  • C6H5CH2CHO

  • C6H5CHO

  • CH3CH2CH2CHO

  • CH3CH2CH2CHO



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