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CBSE

Subject

Chemistry
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NEET Chemistry : Amines

Multiple Choice Questions

1.

Consider the nitration of benzene using mixed conc. H2SO4 and HNO3. If a large amount of KHSO4 is added to the mixture, the rate of nitration will be

  • slower

  • uncharge

  • doubled

  • doubled



2.

The electrolytic reduction of nitrobenzene in strongly acidic medium produces

  • p-aminophenol

  • azoxybenzene

  • azobenzene

  • aniline



3.

The product formed by the reaction of an aldehyde with a primary amine is

  • Ketone

  • Carboxylic acid

  • Aromatic acid

  • Aromatic acid



4.

Some meta-directing substituents in aromatic substitution are given. Which one is most deactivating?

  • -Cidentical toN

  • -SO3H

  • -COOH

  • -COOH



5.

Which of the following will most stable diazonium salt RN2+X-?

  • CH3N2+X-

  • C6H5N2+X-

  • CH3CH2N2+X-

  • CH3CH2N2+X-



6.

The correct statement regarding the basicity of arylamines is

  • Arylamines are generally more basic than alkylamines because the nitrogen lone pair electrons are not delocalized by interaction with the aromatic ring pi-electron system

  • Arylamines are generally more basic than alkylamines, because of aryl group

  • Arylamines are generally more basic than alkylamines because the nitrogen atom in arylamines is sp-hydridized.

  • Arylamines are generally more basic than alkylamines because the nitrogen atom in arylamines is sp-hydridized.



7.

Nitrobenzene on reaction with conc. HNO3/H2SO4 at 80-1000C forms which one of the following products?

  • 1,2-dinitrobenzene

  • 1,3- dinitrobenzene

  • 1,4-dinitrobenzene

  • 1,4-dinitrobenzene



8.

In the reaction,

straight H minus straight C identical to CH space rightwards arrow from left parenthesis ii right parenthesis space CH subscript 3 CH subscript 2 Br to left parenthesis straight i right parenthesis space NaNH subscript 2 divided by liq. NH subscript 3 of space straight X
space space space space space space space space space space space space space space space space space space straight X space rightwards arrow from left parenthesis ii right parenthesis space CH subscript 3 CH subscript 2 Br to left parenthesis straight i right parenthesis NaNH subscript 2 divided by liq. NH subscript 3 of space straight Y
X and Y are

  • X=2-butyne; Y= 3-hexyne

  • X=2-butyne;Y=2-hexyne

  • X=1-butyne ;Y = 2-hexyne

  • X=1-butyne ;Y = 2-hexyne



9.

In the following reaction, the product (A) is 




10.

Which of the following compounds will not undergo Friedel -Craft's reaction easily?

  • Cumene

  • Xylene

  • Nitrobenzene

  • Nitrobenzene



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