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CBSE

Subject

Chemistry
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NEET Chemistry : Amines

Multiple Choice Questions

91.

Among the following which one does not act as an intermediate in Hofmann rearrangement?

  • RNCO

  • RCON..

  • RCON..HBr

  • RNC



92.

When acetamide reacts with Br2 and caustic soda , then we get :

  • acetic acid

  • bromoacetic acid

  • methyl amine

  • ethyl amine



93.

Correct order of basic nature is :

  • NH3 > CH3NH2 > C6H5NH2

  • C6H5NH> NH3 > CH3NH2

  • CH3NH> NH3 > C6H5NH2

  • none of the above



94.

Aniline with CHCl3 and KOH on heating gives :

  • isocyanide

  • cyanide

  • phenol

  • salicylic acid



95.

Nitrobenzene on treatment with zinc dust and aqueous ammonium chloride gives

  • C6H5N =N-C6H5

  • C6H5NH2

  • C6H5NO

  • C6H5NHOH.



96.

Pyridine is less basic than triethylamine because

  • pyridine has aromatic character

  • nitrogen in pyridine is sp2 hybridised

  • pyridine is a cyclic system

  • in pyridine, lone pair of nitrogen is delocalised



97.

Which of the following amines, can give N-nitrosoamine on treatment with HNO2?



98.

Which of the following statement is true?

  • Trimethyl amines form a soluble compound with Hinsberg reagent and KOH.

  • Dimethylamines react with KOH and phenol to form an azo dye.

  • Methylamine reacts with nitrous acid and liberates N2 from aq. soln.

  • None of these



99.

Assertion: Anilinium chloride is more acidic than ammonium chloride.

Reason : Anilinium chloride is resonance stabilised.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.



100.

The following sequence of reactions on A gives



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