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CBSE

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Chemistry
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NEET Chemistry : Coordination Compounds

Multiple Choice Questions

41.

Correct increasing order for the wavelengths of absorption in the visible region for the complexes of Co3+ is

  • [Co(en)3]3+, [Co(NH3)6]3+, [Co(H2O)6]3+

  • [Co(H2O)6]3+, [Co(en)3]3+, [Co(NH3)6]3+

  • [Co(H2O)6]3+, [Co(NH3)6]3+, [Co(en)3]3+

  • [Co(H2O)6]3+, [Co(NH3)6]3+, [Co(en)3]3+



42.

Which of the following is not chiral 

  • 2-butanol

  • 2,3 -dibromo pentane

  • 3- bromopentane

  • 3- bromopentane



43.

The d-electron configuration of Cr3+, Mn2+, Fe2+ and Ni2+ are 3d4, 3d5, 3d6 and 3d8 respectively. Which one of the following aqua complexes will exhibit the minimum paramagnetic behaviour?

(At. no. Cr = 24, Mn = 25, Fe = 26, Ni = 28)

  • [Mn(H2O)6]2+

  • [Fe(H2O)6]2+

  • [Ni(H2O)6]2+

  • [Ni(H2O)6]2+



44.

CH3-CHCl-CH2-CH3 has a chiral centre. Which one of the following represents its R configuration?



45.

The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexes: CoCl3.6NH3, CoCl3.5NH3, CoCl3.4NH3 respectively is

  • 1 AgCl, 3 AgCl, 2 AgCl

  • 3 AgCl, 1 AgCl, 2 AgCl

  • 3 AgCl, 2 AgCl, 1 AgCl

  • 3 AgCl, 2 AgCl, 1 AgCl



46.

The number of unpaired electrons in a paramagnetic  diatomic molecule of an element with atomic number 6 is:

  • 2

  • 3

  • 4

  • 4



47.

[Co(NH3)4(NO2)2]Cl exhibits:

  • linkage isomerism, ionisation isomerism and optical isomerism

  • Linkage isomerism, ionisation isomerism and geometrical isomerism

  • ionization isomerism, geometrical isomerism and optical isomerism

  • ionization isomerism, geometrical isomerism and optical isomerism



48.

[Cr(H2O)6]Cl3 (at. no. of Cr = 24) has a magnetic moment of 3.83 BM, the correct distribution of 3d electrons in the chromium of the complex is:

  • 3 straight d subscript straight x squared minus straight y squared end subscript superscript 1 comma space 3 straight d subscript straight z squared end subscript superscript 1 comma space 3 straight d subscript xz superscript 1
  • 3 straight d subscript xy superscript 1 comma space 3 straight d subscript x squared minus y squared end subscript superscript 1 comma space 3 straight d subscript yz superscript 1
  • 3 straight d subscript xy superscript 1 comma space 3 straight d subscript zy superscript 1 comma space 3 straight d subscript zx superscript 1
  • 3 straight d subscript xy superscript 1 comma space 3 straight d subscript zy superscript 1 comma space 3 straight d subscript zx superscript 1


49.

In which of the following pairs are both the ions coloured in aqueous solution?

(At. no.: Sc = 21, Ti = 22, Ni = 28, Cu = 29, Co = 2)

  • Ni2+, Ti3+

  • Sc3+, Ti3+

  • Sc3+,Co2+

  • Sc3+,Co2+



50.

An example of a sigma bonded organometallic compound is :

  • Ruthenocene

  • Grignard's reagent

  • Ferrocene

  • Ferrocene



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