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CBSE

Subject

Chemistry
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NEET Chemistry : Coordination Compounds

Multiple Choice Questions

51.

Pick out the correct statement with respect
[Mn(CN)6]3–

  • It is sp3d2 hybridised and octahedral

  • It is sp3d2 hybridised and tetrahedral

  • It is d2sp3 hybridised and octahedral

  • It is d2sp3 hybridised and octahedral



52.

Sulphur reacts with chlorine in 1:2 ratio and forms X. Hydrolysis of X gives a sulphur compound Y. The hybridization of the central atom in the anion Y is

  • sp3

  • sp2

  • sp3d

  • sp



53.

Iron carbonyl, Fe(CO)5 is

  • Tetranuclear

  • Mononuclear

  • Dinuclear

  • Trinuclear



54.

The geometry and magnetic behaviour of the complex [Ni(CO)4] are

  • Square planar geometry and diamagnetic

  • Tetrahedral geometry and diamagnetic

  • Tetrahedral geometry and paramagnetic

  • Square planar geometry and paramagnetic



55.

Which one of the following ions exhibits d-d transition and paramagnetism as well?

  • CrO42-

  • Cr2O72-

  • MnO42-

  • MnO4-



56.

Which of the following compound is not coloured?

  • Na2CuCl

  • Na2Cd.Cl4

  • FeSO4

  • VI3



57.

Match the metal ions given in Column I with the spin magnetic moments of the ions given in Column II and assign the correct code :

Column I Column II
a. Co3+ i. 8 BM
b. Cr3+ ii. 35 BM
c. Fe3+ iii. 3 BM
d. Ni2+ iv. 24 BM
    v. 15 BM

  • a b c d
    iv v ii i
  • a b c d
    i ii iii iv
  • a b c d
    iii v i ii
  • a b c d
    iv i ii iii


58.

Consider the following species:
CN+, CN, NO and CN

Which one of these will have the highest bond order?

  • NO

  • CN-

  • CN

  • CN+



59.

The type of isomerism shown by the complex [CoCl2(en)2] is

  • Geometrical isomerism

  • Coordination isomerism

  • Linkage isomerism

  • Ionization isomerism



60.

Which of the following coordination compounds would exhibit optical isomerism?

  • Pentamminentirocobalt (III) iodide

  • Tris-(ethylenediamine) cobalt (III) bromide

  • Trans-dicyanobis (ethylenediamine)

  • Diamminedinitroplatinum (II)



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