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CBSE

Subject

Chemistry
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NEET Chemistry : Electrochemistry

Multiple Choice Questions

21.

The efficiency of a fuel cell is given by:

  • fraction numerator increment straight H over denominator increment straight G end fraction
  • fraction numerator increment straight G over denominator increment straight S end fraction
  • fraction numerator increment straight G over denominator increment straight H end fraction
  • fraction numerator increment straight G over denominator increment straight H end fraction


22.

Kohlrausch's law states that at

  • finite dilution, each ion makes a definite contribution to the equivalent conductance of an electrolyte, whatever be the nature of the other ion of the electrolyte.

  • infinite dilution, each ion makes a definite contribution to the equivalent conductance of an electrolyte depending on the nature of the other ion of the electrolyte.

  • infinite dilution, each ion makes a definite contribution to the conductance of an electrolyte whatever be the nature of the other ions of the electrolyte.

  • infinite dilution, each ion makes a definite contribution to the conductance of an electrolyte whatever be the nature of the other ions of the electrolyte.



23.

Standard free energies of formation (in kJ/mol) at 298 K are -237.2, 394.4 and -8.2 for H2O (l), CO2 (g) and pentane (g),  respectively. The value of Ecello for pentane-oxygen fuel cell is

  • 1.968 V

  • 2.0968 V

  • 1.0968 V

  • 1.0968 V



24.

The values of ΔH and ΔSfor the reaction, C(graphite) + CO2  → 2 CO (g) are 170 kJ and 170 JK-1 respectively. This reaction will be spontaneous at 

  • 710 K

  • 910 K

  • 1110 K

  • 1110 K



25.

If straight E to the power of straight o subscript Fe to the power of 2 plus end exponent divided by Fe end subscript space equals space minus space 0.441 space straight V space and space straight E to the power of straight o subscript Fe to the power of 3 plus end exponent divided by Fe to the power of 2 plus end exponent end subscript space equals space 0.771 space space straight V comma the standard emf of the reaction:

Fe + 2 Fe3+ →3Fe2+

will be:

  • 0.330 V

  • 1.653 V

  • 1.212 V
  • 1.212 V


26.

Al2O3 is reduced by electrolysis at low potentials and high currents. If 4.5 x 104 An of current is passed through molten Al2O3 for 6h, what mass of aluminium is produced? (Assume 100% current efficiency, at.mass of Al = 27 g mol-1)

  • 9.0 x 103 g

  • 8.1 x 104 g

  • 2.4 x 105

  • 2.4 x 105



27.

The equilibrium constant of the reaction:

Cu (s) + 2 Ag+ (aq) →  Cu2+ (aq) + 2 Ag (s);

Eo = 0.46 V at 298 K

  • 2.4 x 1010

  • 2.0 x 1010

  • 4.0 x 1010

  • 4.0 x 1010



28.

For vaporisation of water at 1 atm pressure, the values of ΔH and ΔS are 40.63 kJ mol- and 108.8 JK-1 mol-1, respectively. The temperature when Gibbs energy change (ΔG) for this transformation will be zero, is

  • 273.14 K

  • 393.4 K 

  • 373.4 K 

  • 373.4 K 



29.

The equivalent conductance of M/32 solution of weak monobasic acid is 8.0 ohm-cm2 and at infinite dilution is 400 ohm-cm2. The dissociation constant of this acid is

  • 1.25 x 10-5

  • 1.25 x 10-6

  • 6.25 x 10-4

  • 6.25 x 10-4



30.

Given, 
(i) Cu2+ + 2e- → Cu,     Eo = 0.337 V

(ii) Cu2+ +e- → Cu+, Eo = 0.153

Electrode potential, Eo for the reaction,
Cu +e- →Cu, will be 

  • 0.52 V

  • 0.90 V

  • 0.30 V

  • 0.30 V



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