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CBSE

Subject

Chemistry
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NEET Chemistry : Electrochemistry

Multiple Choice Questions

91.

Assertion: Conductivity of all electrolytes decreases on dilution.

Reason: On dilution number of ions per unit volume decreases.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.



92.

For Zn2+| Zn, E= -0.76 then EMF of the cell Zn/Zn2+(+1M)|2H+ (1M)| H2(1 atm) will be

  • -0.76 V

  • 0.76 V

  • 0.38 V

  • -0.38 V



93.

Electrode potential of hydrogen electrode is 18 mV, then [H+] is

  • 0.2

  • 1

  • 2

  • 5



94.

Assertion : Sodiumacetate on Kolbe's electrolysis gives methane.

Reason : Methyl free radical is formed at cathode.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.



95.

Assertion : Magnesium is extracted by the electrolysis of fused mixture of MgCl2, NaCl and CaCl2.

Reason : Calcium chloride acts as a reducing agent.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.



96.

If a salt bridge is removed between the half cells , the voltage :

  • decreases to zero

  • increases

  • increases rapidly

  • do not change



97.

During electrochemical process :

  • Gibbs free energy increases

  • Gibbs free energy remains constant

  • no prediction can' be made about Gibbs free energy

  • Gibbs free energy decreases



98.

A factory produces 40 kg of calcium in two hours by electrolysis. How much aluminium can be produced by same current in 2 hours if current efficiency is 50%?

  • 22 kg

  • 18 kg

  • 9 kg

  • 27 kg



99.

The standard emf of a cell , involving one electron change is found to be 0.591 V at 25o C . The equilibrium constant of the reaction is :

(F = 96500 C mol-1 , R = 8.314 JK-1mol-1)

  • 1.0 x 101

  • 1.0 x 105

  • 1.0 x 1010

  • 1.0 x 1030



100.

A complex PtCl4.5NH3, shows a molar conductance of 402 ohm-1 cm2mol-1 in water and precipitates three moles ofAgCl with AgNOsolution. The formula of the complex is

  • [Pt(NH3)6]Cl4

  • [Pt(NH3)4Cl2]Cl2

  • [Pt(NH3)5Cl]Cl3

  • [Pt(NH3)3Cl3]Cl



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