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CBSE

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Chemistry
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NEET Chemistry : Equilibrium

Multiple Choice Questions

61.

For the homogeneous reaction,

4NH3 + 5O2  4NO + 6H2O

the equilibrium constant Kc has the units

  • conc.+10

  • conc.+1

  • conc.-1

  • it is dimensionless



62.

R - CH2 - CH2 - OH can be converted into RCH2CH2COOH by the following sequence of steps.

  • PBr3, KCN, H2 /Pt

  • PBr3, KCN, H3O+

  • HCN, PBr3, H3O+

  • KCN, H3O+



63.

At equilibrium, the rate of dissolution of a solid solute in a volatile liquid solvent is

  • less than the rate of crystallisation

  • greater than the rate of crystallisation

  • equal to the rate of crytallisation

  • zero



64.

Ig Ag+ + 2NH3 Ag (NH3)2+ ; K1 = 1.7 x 107

Ag+ Cl-  AgCl; K2 = 5.4 x 109

Then, for AgCl + 2NH3 [Ag(NH3)2]+ + Cl- equilibrium constant will be

  • 0.68 x 10-3

  • 5.2 x 10-17

  • 0.31 x 10-2

  • 3.1 x 10-2



65.

Ammonia is a Lewis base and it forms complexes with many cations. Which one of the following cations does not form a complex with ammonia?

  • Ag+

  • Cu2+

  • Cd2+

  • Pb2+



66.

For the following equilibrium (omitting charges)

I. M + Cl  MCl, Keqβ1

II. MCl + Cl MCl2, Keq = β2

III. MCl2 +Cl  MCl3 ,Keq  = β3

IV. M + 3Cl  MCl3 , Keq = K

then relationship between K, β1 , β2 and β3

  • K = β1β2β3

  • log K = log β1 + log β2 + log β3

  • pk = pβ1 + pβ2 + pβ3

  • All of the above



67.

What percentage of β-D-(+-glucopyranose is found at equilibrium in the aqueous solution?

  • 64%

  • 36%

  • 100%

  • 50%



68.

pKa of acetic acid and pKb of ammonium hydroxide are 4.76 and 4.75 respectively. Calculate the pH of ammonium acetate solution.

  • 6.02

  • 7.005

  • 8

  • 5.602



69.

The value of Kc for the reaction,

2A  B + C is 2 x 10-3. At a given time, if the composition of reaction mixture is [A] = [B] = [C] = 3 x 10-3 M. Which is true?

  • The reaction will proceed in forward direction

  • The reaction will proceed in backward direction

  • The reaction will proceed in any direction

  • None of the above



70.

H and S for the rreaction,

Ag2O(s) 2Ag(s) + 12 O2 (g) are 30.56 kJ mol-1 and 66.00 JK-1 mol-1 respectively. The temperature at which the free energy change for the reaction will be zero is

  • 3528 K

  • 463 K

  • 73 K

  • 144 K



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