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CBSE

Subject

Chemistry
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NEET Chemistry : Equilibrium

Multiple Choice Questions

111.

0.1 M solution of CH3COOH should be diluted to how many times so that pH is doubled ?

  • 4.0 times

  • 5.55 x 104 times

  • 5.55 x 106 times

  • 10-2 times



112.

Assertion : The second dissociation constant of fumaric acid is greater than maleic acid.

Reason : Higher the dissociation constant of acid, more is the acidic character.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false.

  • If both assertion and reason are false



113.

Ka for HCN is 5 x 10-10 at 25°C. For maintaining a constant pH = 9, the volume of 5 M KCN solution required to be added to 10 mL of 2 M HCN solution is

  • 4 mL

  • 2.5 mL

  • 2 mL

  • 6.4 mL



114.

The temperature dependence of a reaction is represented by the Arrhenius equation: 

ln k = -EaRT+ln A

Which among the following is wrong conclusion about the given plot?

  • Intercept of the line= ln A

  • Slope = -EaRT

  • Reaction with high activation energy is more temperature sensitive than that of low activation energy (Ea).

  • Slope = - EaR



115.

KP for the reaction A  B is 4. If initially only A is present then what will be the partial pressure of B after equilibrium?

  • 1.2

  • 0.8

  • 0.6

  • 1



116.

Which of the following oxoacids of phosphorus is a reducing agent and a monobasic acid as well?

  • H4P2O5

  • HPO3

  • H3PO3

  • H3PO2



117.

Calculate the overall complex dissociation equilibrium constant for the [Cu(NH3)4]2+ ions, given that stability  constant (β4) for this complex is 2.1 × 1013.

  • 8.27 × 10-13

  • 4.76 × 10-14

  • 2.39 × 10-7

  • 1.83 × 1014



118.

If the equilibrium constant of the reaction of weak acid HA with strong base is 109 then pH of 0.l M NaA is :

  • 5

  • 9

  • 7

  • 8



119.

Which of the following compounds is the weakest Bronsted base ?



120.

NO2 (brown colour gas) exists in equilibrium with N2O4 (colourless gas) as given by chemical equation.

2NO2(brown)  N2O4(colourless)

Mixture is slightly brown due to existence of NO2. If pressure is increased :

  • colour intensity is increased

  • colour intensity is decreased

  • colour intensity first increases and then decreases

  • No change in colour intensity



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