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CBSE

Subject

Chemistry
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NEET Chemistry : Haloalkanes and Haloarenes

Multiple Choice Questions

51.

Identify the major product 'X' obtained in the following reaction.

2, 3-dimethyl butan-2-ol conc. H2SO4 X



52.

Which of the following statement is correct ?

  • +I group stabilises a carbocation

  • +I group stabilises a carbanion

  • -I group stabilises a carbocation

  • -I group stabilises a free radical



53.

t-butyl chloride preferably undergo hydrolysis by

  • SN1 mechanism

  • SN2 mechanism

  • Any of (a) and (b)

  • None of these



54.

Which of the following can give a Grignard reagent when reacted with magnesium in dry ether?

  • C2H6

  • C2H5Cl

  • C2H5OH

  • C2H5CN



55.

Addition ofwater to alkynes occurs in acidic medium and in the presence of Hg2+ ions as a catalyst. Which of the following products will be formed on addition of water to but-1-yne under these conditions?

  • CH3CH2CH2CHO

  • CH3CH2COCH3

  • CH3CH2COOH

  • CH3COOH + HCHO



56.

Which one of the following acts as a nucleophile?

  • (CH3)3N

  • BF3

  • N+O2

  • CH3 - C+ = O



57.

CH3CHO +HCHO HeatDil. NaOH A H3O+HCN B

The structure of compound B is



58.

Which one of these is not true for benzene?

  • It forms only one type of mono-substituted product

  • There are three carbon-carbon single bonds and three carbon-carbon double bonds

  • Heat of hydrogenation of benzene is less than its theoretical value

  • The bond angle between carbon-carbon bonds is 120°



59.

Iodoform gives a precipitate with AgNO3 on heating but chloroform does not because

  • C - I bond in iodoform is weak and C - Cl bond in chloroform is strong

  • chloroform is covalent

  • iodoform is ionic

  • None of the above



60.

Which of the following compounds have highest melting point?

  • Only I

  • Only II

  • I and II

  • II and III



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