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CBSE

Subject

Chemistry
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NEET Chemistry : Haloalkanes and Haloarenes

Multiple Choice Questions

131.

Assertion : Hydroxyketones are not directly used in Grignard reaction.

Reason : Grignard reagents react with hydroxyl group.

  • If both assertion and reason are true and the reason is the correct explanation of the assertion.

  • If both assertion and reason are true and the reason is not the correct explanation of the assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.



132.

Assertion : 2-bromobutane on reaction with sodium ethoxide in ethanol gives 1-butene as a major product.

Reason : 1-butene is more stable than 2-butene.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.



133.

Which ofthe following is involved in Sandmeyer's reaction ?

  • Ferrous salt

  • Diazonium salt

  • Ammonium salt

  • Cupromonium salt



134.

Assertion : Trans-2-butene on reaction with Br2 gives meso-2,3-dibromobutane.

Reason : The reaction involves syn -addition of bromine.

  • If both assertion and reason are true and the reason is the correct explanation of the assertion.

  • If both assertion and reason are true and the reason is not the correct explanation of the assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.



135.

Assertion : Benzyl bromide when kept in acetone water it produces benzyl alcohol.

Reason : The reaction follows SN2 mechanism.

  • If both assertion and reason are true and the reason is the correct explanation of the assertion.

  • If both assertion and reason are true and the reason is not the correct explanation of the assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.



136.

Assertion : Rate of hydrolysis of methyl chloride to methanol is higher in DMF than in water.

Reason : Hydrolysis of methyl chloride follows second order kinetics.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.



137.

Assertion : The major products formed by heating C6H5CH2OCH, with HI are C6H5CH2I and CH3OH.

Reason : Benzyl cation is more stable than methyl cation.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.



138.

CH3-CH2-Cl alc. KOH A, the product is :

  • CH3CH2OK

  • CH3CHO

  • CH3CH2OCH2CH3

  • CH2=CH2



139.

Among the following the dissociation constant is highest for

  • C6H5OH

  • C6H5CH2OH

  • CH3CCH

  • CH3NH3+Cl



140.

The reaction :

C2H5OH  SOCl2 Pyridine C2H5Cl + SO2 + HCl is known as :

  • Kharasch effect

  • Williamson's synthesis

  • Darzen's procedure

  • Hunsdiecker reaction



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