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CBSE

Subject

Chemistry
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NEET Chemistry : Organic Chemistry – Some Basic Principles and Techniques

Multiple Choice Questions

121.

The strained tetracyclic alkane is isomerize thermally to the cyclic alkene. The reaction involves

  • free radical

  • carbocation

  • carbanion

  • carbene.



122.

Assertion : C(CH3)3-CH2-Br + NaOH C(CH3)2OH-CH2-CH3

Reason : It follows with formation of more stable carbocation.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.



123.

Which of the following conditions is not correct for resonating structures?

  • The contributing structures must have the same number of unpaired electrons.

  • The contributing structures should have similar energies.

  • The contributing structures should be so written that unlike charges reside on atoms that are far apart.

  • The positive charge should be present on the electropositive element and the negative charge on the electronegative element.



124.

Which is optically inactive?



125.

How many chiral carbonatoms are present in 2 , 3 , 4 - trichloropentane ?

  • 4

  • 1

  • 2

  • 3



126.

Best method to form aromatic iodide is

  • ArN2+ + KI 

  • RNH2 + I2 

  • ArN2+ + KI 

  • ArN2+ + PI3 



127.

+ I effect is shown by :

  • -CH3

  • -Br

  • -Cl

  • -NO2



128.

How much amount of CuSO4.5H2O is required for liberation of 2.54 g of I2 when titrated with KI?

  • 2.5 gm

  • 4.99 gm

  • 2.4 gm

  • 1.2 gm



129.

Find the number of stereoisomers of 1,2-dihydroxy cyclopentane.

  • 1

  • 2

  • 3

  • 4



130.

Decreasing order of nucleophilicity is

  • OH- > NH2- > CH3O- > RNH2

  • NH2- > OH- > CH3O- > RNH2

  • NH2- > CH3O- > OH- > RNH2

  • CH3O- > NH2- > OH- > RNH2



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