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CBSE

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Chemistry
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NEET Chemistry : Organic Chemistry – Some Basic Principles and Techniques

Multiple Choice Questions

121.

Assertion : C(CH3)3-CH2-Br + NaOH C(CH3)2OH-CH2-CH3

Reason : It follows with formation of more stable carbocation.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.



122.

Which is optically inactive?



123.

The strained tetracyclic alkane is isomerize thermally to the cyclic alkene. The reaction involves

  • free radical

  • carbocation

  • carbanion

  • carbene.



124.

Best method to form aromatic iodide is

  • ArN2+ + KI 

  • RNH2 + I2 

  • ArN2+ + KI 

  • ArN2+ + PI3 



125.

How many chiral carbonatoms are present in 2 , 3 , 4 - trichloropentane ?

  • 4

  • 1

  • 2

  • 3



126.

Decreasing order of nucleophilicity is

  • OH- > NH2- > CH3O- > RNH2

  • NH2- > OH- > CH3O- > RNH2

  • NH2- > CH3O- > OH- > RNH2

  • CH3O- > NH2- > OH- > RNH2



127.

Which of the following conditions is not correct for resonating structures?

  • The contributing structures must have the same number of unpaired electrons.

  • The contributing structures should have similar energies.

  • The contributing structures should be so written that unlike charges reside on atoms that are far apart.

  • The positive charge should be present on the electropositive element and the negative charge on the electronegative element.



128.

Find the number of stereoisomers of 1,2-dihydroxy cyclopentane.

  • 1

  • 2

  • 3

  • 4



129.

+ I effect is shown by :

  • -CH3

  • -Br

  • -Cl

  • -NO2



130.

How much amount of CuSO4.5H2O is required for liberation of 2.54 g of I2 when titrated with KI?

  • 2.5 gm

  • 4.99 gm

  • 2.4 gm

  • 1.2 gm



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