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CBSE

Subject

Chemistry
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NEET Chemistry : The Solid State

Multiple Choice Questions

21.

The fraction of totoal volume occupied by the atoms present in a simple cube is: 

  • π/6

  • fraction numerator straight pi over denominator 3 square root of 2 end fraction
  • fraction numerator straight pi over denominator 4 square root of 2 end fraction
  • fraction numerator straight pi over denominator 4 square root of 2 end fraction


22.

If NaCl is doped with 10-4 mol% of SrCl2 the concentration of cation vacancies will be 
(NA = 6.02 x 1023 mol-1):

  • 6.02 x 1015 mol-1

  • 6.02 x 1016 mol-1

  • 6.02 x 1017

  • 6.02 x 1017



23.

CsBr crystallises in a body centred cubic lattice. The unit cell length is 436.6 pm. Given that the atomic mass of Cs - 133 and that of Br = 80 amu and Avogadro number being
6.02 x 1023 mol-1, the density of CsBr is:

  • 42.5 g/cm3

  • 0.425 g/cm3

  • 8.25 g/cm3

  • 8.25 g/cm3



24.

The appearance of colour is solid alkali metal halides is generally due to:

  • F- centres

  • Schottky defect

  • Frenkel defect

  • Frenkel defect



25.

Which is the incorrect statement?

  • FeO0.98 has non stoichiometric metal deficiency defect

  • Density decreases in case of crystals with Schottky's defect

  • NaCl(s) is insulator, silicon is semiconductor,silver is conductor, quartz is piezo electric crystal

  • NaCl(s) is insulator, silicon is semiconductor,silver is conductor, quartz is piezo electric crystal



26.

Iron exhibits bcc structure at room temperature. Above 900°C, it transforms to fcc structure. The ratio of density of iron at room temperature to that at 900°C (assuming molar mass and atomic radii of iron remains constant with temperature) is

  • 32

  • 4332

  • 1/2

  • 3342



27.

A solid AB has a NaCl structure. If the radius of cation A+ is 170 pm, then the maximum possible radius of the anion B- is

  • 397.4 pm

  • 347.9 pm

  • 210.9 pm

  • 410.6 pm



28.

If oxide ions are arranged in hep and the aluminium ions occupy two thirds of octahedral voids. What will be the formula of the compound?

  • AlO3 

  • Al2O3

  • (Al2O3)2

  • Al3O4



29.

Percentage of free space in a body centre cubic unit cell is

  • 30%

  • 32%

  • 34%

  • 28%



30.

Ferrous oxide has a cubic structure. The length of edge of the unit cell is 5 Å and the density of the oxide is 4 .0 g cm-3 Then the number of Fe2+ and O2- ions present in each unit cell will be

  • four Fe2+ and two O2-

  • four Fe2+ and four O2-

  • two Fe2+ and four O2-

  • two Fe2+ and two O2-



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