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CBSE

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Chemistry
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NEET Chemistry : Thermodynamics

Multiple Choice Questions

31.

According to the first law of thermodynamics which of the following quantities represents the change in a state function?

  • qrev

  • qrev - Wrev

  • qrevWrev

  • qrev + Wrev



32.

The energy released when 6 moles of octane is burnt in air will be [Given, ΔHf for CO2 (g). H2O(g) and C8H18 (l), respectively are -490, -240 and +160J/mol]

  • -37.4 kJ

  • -20 kJ

  • -6.2 kJ

  • -35.5 kJ



33.

For the reaction,

H2O(l)  H2O(g)

at 373 K and 1 atm pressure

  • H = 0

  • E = 0

  • H = TS

  • H = E



34.

Which of the following is the increasing order of enthalpy of vaporization?

  • NH3, PH3, AsH3

  • AsH3, PH3 NH3

  • NH3, AsH3, PH3

  • PH3, AsH3, NH3



35.

The heat of formation of CO(g) and CO2 (g)are H = -110 and H = - 393 kJ mol-1 respectively. What is the heat of reaction (H) (in kJ mol-1) for the following reaction?

CO (g) + 12O2 (g)  CO2(g)

  • -504

  • -142.5

  • -283

  • 504



36.

What is the H of the reaction?

CH2Cl2 (g) C (g) + 2H (g) + 2Cl (g)

The average bond energies of C-Cl bond and C-H bond are 416 kJ and 325 kJ mol-1 respectively.

  • 1482 kJ

  • 1482 J

  • 1492 kJ

  • 1492 J



37.

32 O2(g) O3(g); Kp for this reaction is 2.47 x 10-29. At 298 K, rG° for conversion of oxygen to ozone will be

  • 100 kJ mol-1

  • 150 kJ mol-1

  • 163 kJ mol-1

  • 2303 kJ mol-1



38.

For the process to occur under adiabatic conditions, the correct condition is

  • T = 0

  • p = 0

  • q = 0 

  • W = 0



39.

If for a given substance, melting point is TB and freezing point is TA then correct variation of entropy by graph between entropy change and temperature is



40.

Graphite is a

  • molecular solid

  • covalent solid

  • ionic solid

  • metallic solid



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