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CBSE

Subject

Chemistry
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NEET Chemistry : Thermodynamics

Multiple Choice Questions

131.

Which of the following is correct?

  • Evaporation of water causes an increase in disorder of the system

  • Melting of ice causes a decrease in the randomness of the system

  • Condensation of steam causes an increase in disorder of the system

  • There is practically no change in the randomness of the system when water is evaporated



132.

Equal volumes of molar hydrochloric acid 'and sulphuric acid are neutralized by dilute NaOH solution and x kcal and y kcal of heat are liberated respectively. Which of the following is true ?

  • x = y

  • x =y/2

  • x = 2y

  • none of these



133.

The product p of the nuclear reaction

U92235 + n01  p + Kr3692 + 3n01, is

  • Sr56141

  • La56141

  • Ba56141

  • Cs56141



134.

The second law of thermodynamic says that in a cyclic process

  • work cannot be converted into heat

  • heat cannot be converted into work

  • work cannot be completely converted into heat

  • heat cannot be completely converted into work



135.

For which reaction change of entropy will be positive?

  • H2(g) + I2(g)  2HI (g)

  • HCl (g) + NH3 (g)  NH4Cl (s)

  • NH4NO3 (s)  N2O (g) + 2H2O (g)

  • MgO(s) + H2(g)  Mg(s) + H2O(l)



136.

Which of the following thermodynamic relation is correct ?

  • dG = Vdp- SdT

  • dE = pdV + TdS

  • dH = -Vdp + Tds

  • dG = Vdp + SdT



137.

The amount of the heat released when 20 mL 0.5 M NaOH is mixed with 100 ml 0.1 M HCl is x kJ. The heat of neutralisation is:

  • - 100 x kJ/mol

  • - 50 x kJ/mol

  • + 100 x kJ/mol

  • + 50 x kJ/mol



138.

Given that,

    C + O2 → CO2H = -x kJ

2CO + O2 → 2CO2 ;H = -y kJ

The heat of formation of carbon monoxide will be

  • y - 2x2

  • y + 2x

  • 2x - y

  • 2x - y2



139.

Calculate Kc for the reversible process given below if Kp = 167 and T = 800°C

CaCO3 (s)  CaO (s) + CO2 (g)

  • 1.95

  • 1.85

  • 1.89

  • 1.60



140.

For a spontaneous process, the correct statement(s) is (are)

  • (Gsystem)T, p > 0

  • (Ssystem) + (Ssurroundings) > 0

  • (Gsystem)T, p < 0

  • (Usystem)t, v > 0



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