Give reasons:Thermal stability decreases from H2O to H2Te. from

Subject

Chemistry

Class

CBSE Class 12

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 Multiple Choice QuestionsShort Answer Type

21.

Write one difference in each of the following :
Homogeneous catalysis and Heterogeneous catalysis

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22.

Following data are obtained for the reaction :
N2O5 → 2NO2 + ½O2

t/s 0 300 600
[N2O5]/mol L–1 1.6 × 10–2 0.8 × 10–2 0.4 × 10–2

(a) Show that it follows first order reaction.
(b) Calculate the half-life.
(Given log 2 = 0.3010 log 4 = 0.6021)

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23.

Write the principle of the method used for the refining of germanium.

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24.

Out of PbS and PbCO3 (ores of lead), which one is concentrated by froth flotation process preferably?

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25.
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26.

Give reasons:
Thermal stability decreases from H2O to H2Te.


The thermal stability of the hydrides of group 16 elements decreases down the group, i.e., H2O > H2S > H2Se > H­2Te > H2Po. This is because M-H bond dissociation energy decreases down the group with the increase in the size of a central atom. 

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27.

Give reasons:
Fluoride ion has higher hydration enthalpy than chloride ion.

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28.

Give reasons:
Nitrogen does not form pentahalide.

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29.

Account for the following :
Transition metals form large number of complex compounds.

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30.

Account for the following :
The lowest oxide of transition metal is basic whereas the highest oxide is
amphoteric or acidic.

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