The standard free energy change of a reaction is ∆G&de

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

1.

The number of hydrogen atoms present in 25.6 g of sucrose (C12H22O11) which has a molar mass of 342.3 g is

  • 22 × 1023

  • 9.91 × 1023

  • 11 × 1023

  • 44 × 1023 H atoms


2.

The oxidation number of oxygen in KO3, Na2O2 is

  • 3, 2

  • 1, 0

  • 0, 1

  • -0.33, -1


3.

The number of formula units of calcium fluoride, CaF2 present in 146.4 g of CaF(the molar mass of CaF2is 78.08 g/mol) is

  • 1.129 × 1024 CaF2

  • 1.146 × 1024 CaF2

  • 7.808 × 1024 CaF2

  • 1.877 × 1024 CaF2


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4.

The standard free energy change of a reaction is G°= -115 kJ at 298 K. Calculate the equilibrium constant Kp in log Kp (R =8.314 JK -1mol-1 ).

  • 20.16

  • 2.303

  • 2.016

  • 13.83


A.

20.16

G°= -115 × 103 J,T = 298 K, R = 8.314 JK-1 mol-1-G°= 2.303RT log10Kp-(-115 × 103 )= 2.303×8.314× 298 log10Kplog10Kp=1150002.303×8.314× 298log10Kp= 20.16


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5.

If an endothermic reaction occurs spontaneously at constant temperature (T) and pressure (p), then which of the following is true?

  • G > 0

  • H < 0

  • S > 0

  • S < 0


6.

A spontaneous process is one in which the system suffer

  • no energy change

  • a lowering of free energy

  • a lowering of entropy

  • an increase in internal energy


7.

CH3CH3 + HNO3 675K ?

  • CH3CH2NO2

  • CH3CH2NO2 + CH3NO2

  • 2CH3NO2

  • CH2= CH2


8.

Diamond is hard because

  • all the four valence electrons are bonded to each carbon atoms by covalent bonds

  • it is a giant molecule

  • it is made up of carbon atoms

  • it cannot be burnt


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9.

The gas evolved on heating alkali formate with soda-lime is

  • CO

  • CO2

  • hydrogen

  • water vapour


10.

The continuous phase contains the dispersed phase throughout, example is

  • water in milk

  • fat in milk

  • water droplets in mist

  • oil in water


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