A buffer solution is prepared by mixing 0.1 M ammonia and 1.0 M ammonium chloride. At 298 K, the pKb of NH4OH is 5.0. The pH of the buffer is
10.0
9.0
6.0
8.0
Among NH3, HNO3, NaN3 and Mg3N2 the number of molecules having nitrogen in negative oxidation state is
1
2
3
4
Born-Haber cycle may be used to calculate
electronegativity
mass number
oxidation number
electron affinity
D.
electron affinity
According to Born-Haber cycle the enthalpy of formation (Hf) of an ionic compound may be given as:
where, I = ionisation energy; S = sublimation energy; E = electron affinity; D = dissociation energy and U = lattice energy of compound
Born-Haber cycle is used to determine the lattice energy of the compound. It also may be used to calculate electron affinity of an element.
The heat of formation for CO2 (g), H2O (l) and CH4 (g) are -400 kJ mol-1, -280 kJ mol-1 and -70 kJ mol-1 respectively. The heat of combustion of CH4 in kJ mol-1 is
890
-160
-890
-90
Oxygen and sulphur both are the member of same group in periodic table but H2O is liquid while H2S is gas because
molecular weight of water is more
electronegativity of sulphur is more
H2S is weak acid
water molecules are having weak hydrogen bonds between them