Impossible orbital among the following is from Chemistry JEE Yea

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

1.

Which one of the followmg has no unpaired electrons?

  • O2-

  • O2+

  • O22-

  • O2


2.

The "spin only'' magnetic moment of Ni2+ in aqueous solution would be [At. no. of Ni = 28]

  • 15 BM

  • 2 BM

  • 8 BM

  • 6 BM


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3.

Impossible orbital among the following is

  • 3f

  • 2p

  • 4d

  • 2s


A.

3f

According to Bohr-Burry's sche,e, maximum number of e- in 3rd orbital = 3n2

                      = 3 (3)2 = 18

and maximum number of e- in

s-subshell = 2

p-subshell = 6

d-subshell = 10

f-subshell = 14

Therefore, 18e- present in 3rd orbital enter in sp, and d subshell. Thereafter, there is no e- available for f-subshell. That's why 3f subshell is not possible.


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4.

The total number of electrons in 18 mL of water (density = 1 g mL-1) is

  • 6.02 × 1025

  • 6.02 × 1024

  • 6.02 ×  18 × 1023

  • 6.02 × 1023


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5.

The number of moles of hydrogen that can be added to 1 mole of an oil is the highest in

  • groundnut oil

  • sunflower seed oil

  • mustard oil

  • linseed oil


6.

The equilibrium constant of a reaction is 0.008 at 298 K. The standard free energy change of the reaction at the same temperature is

  • -11.96 kJ

  • -5.43 kJ

  • -8.46 kJ

  • +11.96 kJ


7.

The correct order of electronegativities of N, O, F and P is

  • F > O > P > N

  • F > O > N > P

  • N > O > F > P

  • F > N > P > O


8.

Which of the following is not a characteristic of a covalent compound?

  • No definite geometry

  • Insoluble in polar solvent

  • Smal difference in electronegativity between the combining atoms

  • Low melting point


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9.

The volume of 0.1 M oxalic acid that can be completely oxidized by 20 mL of 0.025 M KMnO4 solution is

  • 25 mL

  • 12.5 mL

  • 37.5 mL

  • 125 mL


10.

A ligand is a

  • Bronsted acid

  • either a Lewis acid or a Lewis base

  • Lewis base

  • Lewis acid


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