The equilibrium constant of a reaction is 0.008 at 298 K. The sta

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

1.

Which one of the followmg has no unpaired electrons?

  • O2-

  • O2+

  • O22-

  • O2


2.

The "spin only'' magnetic moment of Ni2+ in aqueous solution would be [At. no. of Ni = 28]

  • 15 BM

  • 2 BM

  • 8 BM

  • 6 BM


3.

Impossible orbital among the following is

  • 3f

  • 2p

  • 4d

  • 2s


4.

The total number of electrons in 18 mL of water (density = 1 g mL-1) is

  • 6.02 × 1025

  • 6.02 × 1024

  • 6.02 ×  18 × 1023

  • 6.02 × 1023


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5.

The number of moles of hydrogen that can be added to 1 mole of an oil is the highest in

  • groundnut oil

  • sunflower seed oil

  • mustard oil

  • linseed oil


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6.

The equilibrium constant of a reaction is 0.008 at 298 K. The standard free energy change of the reaction at the same temperature is

  • -11.96 kJ

  • -5.43 kJ

  • -8.46 kJ

  • +11.96 kJ


D.

+11.96 kJ

Standard free energy change, G° = -2.303 RT log K

= -2.303 × 8.314 × 298 × log 0.008

= -2.303 × 8.314 × 298 × (3 log 2 - 3 log 10)

= -2.303 × 8.314 × 298 × (0.903 - 3.0)

= -2.303 × 8.314 × 298 × (-2.097)

= +11965.16 J 

= +11.96 kJ


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7.

The correct order of electronegativities of N, O, F and P is

  • F > O > P > N

  • F > O > N > P

  • N > O > F > P

  • F > N > P > O


8.

Which of the following is not a characteristic of a covalent compound?

  • No definite geometry

  • Insoluble in polar solvent

  • Smal difference in electronegativity between the combining atoms

  • Low melting point


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9.

The volume of 0.1 M oxalic acid that can be completely oxidized by 20 mL of 0.025 M KMnO4 solution is

  • 25 mL

  • 12.5 mL

  • 37.5 mL

  • 125 mL


10.

A ligand is a

  • Bronsted acid

  • either a Lewis acid or a Lewis base

  • Lewis base

  • Lewis acid


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