Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

21.

Alkaline earth's metals are denser than alkali metals, because metallic bonding in alkaline earth's metal is

  • stronger

  • weaker

  • volatile

  • not present


22.

On mixing urea with nitrous acid, the composition of the products is

  • NH2-NH2 + CO2

  • N2 + C + H2O

  • NH3 + CO2 + H2O

  • N2 + CO2 + H2O


23.

Mark out the correct decreasing order of ease of addition of halogen.

  • CH2=CH2 > CH3-CH=CH-CH3 > CH3-C(CH3)=CH2 > (CH3)2C=C(CH3)2

  • (CH3)2C=C(CH3)2 > CH3-C(CH3)=CH2 > CH3-CH=CH-CH3 > CH2=H2

  • (CH3)2C=C(CH3)2 > CH3-CH=CHCH3 > CH3-C(CH3)=CH2 > CH2=CH2

  • CH2=CH2 > CH3-C(CH3)=CH2 > CH3-CH=CH-CH3 > (CH3)2C=C(CH3)2


24.

Transport number of Cl- is least in

  • HCl

  • NaCl

  • KCl

  • CsCl


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25.

Decomposition of H2O2 is a first order reaction. Initially, solution of H2O2 having half-life time 15 min is 16 volume. When solution becomes 1 volume

  • 4 min

  • 15 min

  • 30 min

  • 60 min


26.

What is the two third life of a first order reaction having k = 5.48 × 10-14s-1?

  • 1 × 1013 s

  • 2 × 1013 s

  • 8 × 1013 s

  • 5 × 1014 s


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27.

In a cell that utilises the reaction

Zn (s) + 2H+ (aq) → Zn2+ + H2 (g)

addition of H2SO4 to cathode compartment will

  • lower the E and shift equilibrium to the left

  • lower the E and shift the equilibrium to the right

  • increase the E and shift the equilibrium to the right

  • increase the E and shift the equilibrium to the left


C.

increase the E and shift the equilibrium to the right

Zn (s) + 2H+ → Zn2+ (aq) + H2 (g)

Reaction quotient Q = Zn2+H+2

Corresponding cell is

Zn | Zn2+ Anode (-)(C1) || H+ (aq) | Pt (H2)Cathode (+)And Ecell = Ecell° - 0.05912 log K              = Ecell° - 0.05912 log Zn2+H+2              = Ecell° + 0.05912 log H+Zn2+

If H2SO, is added to cathodic compartment, (towards reactant side), then Q decreases (due to increase in H+).

Hence, equilibrium is displaced towards right and Ecell increases.


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28.

Which of the following solvents are aprotic ?

I. NH3

II. SO2

III. CH3CN

IV. CH3CO2H

  • I, II and III

  • I, III and IV

  • II and III

  • I and III


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29.

The most efficient agent for the absorption of SO3 is

  • 80% H2SO4

  • 98% H2SO4

  • 50% H2SO4

  • 20% H2SO4


30.

Which of the following reaction is used to make a fuel cell?

  • Cd (s) + 2Ni(OH)3 (s) → CdO (s) + 2Ni(OH)2 (s) + H2O (l)

  • 2Fe (s) + O2 (g) + 4H+ (aq) → 2Fe2+ (aq) + 2H2O (l)

  • Pb (s) + PbO2 (s) + 2H2SO4 (aq) → 2PbSO4 (s) + 2H2O (l)

  • 2H2 (g) + O2 (g) → 2H2O (l)


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