The correct order of equivalent conductances at infinite dilution

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

1.

At 25°C, the solubility product of salt of MX2 type is 3.2 × 10-8 in water. The solubility (in mol/L) of MX2 in water at the same temperature will be

  • 1.2 × 10-3

  • 2 × 10-3

  • 3.2 × 10-3

  • 1.75 × 10-3


2.

In SOCl2, the Cl-S-Cl and Cl-S O bond angles are

  • 130° and 115°

  • 106° and 96°

  • 107° and 108°

  • 96° and 106°


3.

In O2 and H2O2 , the O-O bond lengths are 1.21 and 1.48 Å respectively. In ozone, the average O-O bond length is

  • 1.28 Å

  • 1.18 Å

  • 1.44 Å

  • 1.52 Å


4.

The different colours of litmus in acidic, neutral and basic solutions are, respectively.

  • red, orange and blue

  • blue, violet and red

  • red, colourless and blue

  • red, violet and blue


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5.

The correct order of equivalent conductances at infinite dilution in water at room temperature for H+, K+, CH3COO- and HO- ions is

  • HO- > H+ > K+ > CH3COO-

  • H+ > HO- > K+ > CH3COO-

  • H+ > K+ > HO- > CH3COO-

  • H+ > K+ > CH3COO- > HO-


B.

H+ > HO- > K+ > CH3COO-

Equivalent conductance is the conducting power of all the ions produced by one gram equivalent of an electrolyte in a given solution. In case of weak electrlolytes such as CH3COOH, NH4OH etc, ionisation is very small compared to strong electrolytes. Hence, equivalent conductance of weak electrolytes is low. 

Thus, the correct order of equivalent conductance is 

H+ > OH- > K+ > CH3COO-


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6.

The change of entropy (dS) is defined as

  • dS = δqT

  • dHT

  • dS = δqrevT

  • dS = dH - dGT


7.

For a chemical reaction at 27°C, the activation energy is 600 R. The ratio of the rate constants at 327°C to that of at 27°C will be

  • 2

  • 40

  • e

  • e2


8.

A van der Waals' gas may behave ideally when

  • the volume is very low

  • the temperature is very high

  • the pressure is very low

  • the temperature, pressure and volume all are very high


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9.

In diborane, the number of electrons that accounts for bonding in the bridges is

  • six

  • two

  • eight

  • four


10.

At 25°C, pH of a 10-8 M aqueous KOH solution will be

  • 6.0

  • 7.02

  • 8.02

  • 9.02


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