Which of the following has highest electron affinity? from Chemi

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

1.

What is the structure of XeF6?

  • Tetrahedral

  • Distorted octahedral

  • Octahedral

  • None of these


2.

Lowering of vapour pressure is highest for

  • 0.1 M BaCl2

  • 0.1 M glucose

  • 0.1 M MgSO4

  • Urea


3.

The set representing the correct order of ionic radius is

  • Li+ > Be2+ > Na+ > Mg2+

  • Na+ > Li+ > Mg2+ > Be2+

  • Li+ > Na+ > Mg2+ > Be2+

  • Mg2+ > Be2+ > Li+ > Na+


4.

NaOH is a strong base. What will the be pH of 5.0 × 10-2 M NaOH solution? (log 2 = 0.3)

  • 14.00

  • 13.70

  • 13.00

  • 12.70


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5.

The enthalpy of combustion for the H2, cyclohexene and cyclohexane are -241, -3800 and -3920 kJ mol-1 respectively. Heat of hydrogenation of cyclohexene is

  • 121 kJ mol-1

  • -121 kJ mol-1

  • 242 kJ mol-1

  • -242 kJ mol-1


6.

The value of Kc for the dissociation reaction, H2 (g)  2H (g) is 1.2 × 10-42

This equilibrium mixture contains mainly

  • H2 (g)

  • H (g) atom

  • 1.1 M mixture of H2 and H

  • 1.2 M mixture of H2 and H


7.

Ksp of CaSO4 is 4 × 10-12. CaSO4 is precipitated on mixing equal volumes of the following solutions.

  • 3 × 10-10 M CaCl2 and 3 × 10-6 M (NH4)2SO4

  • 4 × 10-6 M CaCl2 and 3 × 10-6 M (NH4)2SO4

  • 6 × 10-6 M CaCl2 and 3 × 10-16 M (NH4)2SO4

  • In all the above cases


8.

Which of the following is the correct decreasing order of oxidation state of nitrogen?

  • HNO3 > NO > NH4Cl > N2

  • HNO3 > NO > N2 > NH4Cl

  • HNO3 > NH4Cl > NO > N2

  • NO > HNO3 > NH4Cl > N2


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9.

Which of the following has highest electron affinity?

  • N

  • O

  • F

  • Cl


D.

Cl

The electron affinities of some of the elements of second period ( i.e. N, O, F, etc) are however, lower than the corresponding elements ( i.e P, S, Cl, etc) of the third period. This is due to the reason that the elements of second period have the smallest atomic sizes amongst  the elements in their respective groups. As a result, there are considerable electron-electron repulsion with the atom itself and hence, the additional electron is not accepted with the same case as compared to the remaining elements in the same group.


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10.

The shape of XeO2F2 molecule is

  • trigonal bipyramidal

  • square planar

  • tetrahedral

  • see-saw


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