A catalyst
changes the equilibrium constant
lowers the activation energy
increases the forward and backward reactions at different speeds
follows same mechanism for the reaction
Which of the following statement is true?
Trimethyl amines form a soluble compound with Hinsberg reagent and KOH.
Dimethylamines react with KOH and phenol to form an azo dye.
Methylamine reacts with nitrous acid and liberates N2 from aq. soln.
None of these
Assertion : Benzene diazonium salt on boiling with water forms phenol.
Reason : C- N bond is polar.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
Assertion : Acetamide has more polar -CO group than in ethyl acetoacetate.
Reason : H2 is more electron donating than C2H5.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
Assertion : Chloral reacts with phenyl chloride to form DDT.
Reason : It is an electrophilic substitution reaction.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
Assertion : Mixture of CH3COOH and CH3COONH4 is an example of acidic buffer.
Reason : Acidic buffer contains equimolar mixture of weak acid and its salt with weak base.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
Assertion : Alkyl iodide can be prepared by treating alkyl chloride/bromide with NaI in acetone.
Reason : NaCl/NaBr are soluble in acetone while NaI is not.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
C.
If assertion is true but reason is false.
This is Finkelstein reaction which involves the conversion of an alkyl chloride/bromide to an alkyl iodide by the addition of sodium iodide in acetone. Because sodium iodide is soluble in acetone and NaCl and NaBr are not. the equilibrium is shifted by the precipitation of insoluble salt.
R - X R - X'
The equilibrium position of the reaction depends on the nucleophilicity of the anion, whether a good leaving group is present and whether one anion is better stabilised than the other in a given solvent.
Assertion : Alpha ()-amino acids exist as internal salt in solution as they have amino and carboxylic acid groups in near vicinity.
Reason: H+ ion given by carboxylic group (-COOH) is captured by amino group (-NH2) having lone pair of electrons.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.