For which reaction change of entropy will be positive?
H2(g) + I2(g) 2HI (g)
HCl (g) + NH3 (g) NH4Cl (s)
NH4NO3 (s) N2O (g) + 2H2O (g)
MgO(s) + H2(g) Mg(s) + H2O(l)
Which of the following acids has the smallest dissociation constant?
CH3CHFCOOH
FCH2CH2COOH
BrCH2CH2COOH
CH3CHBrCOOH
C.
BrCH2CH2COOH
Group or atom attached with -COOH group shows negative inductive effect, makes the acid stronger or acid has the larger dissociation constant.
-Br shows poor negative inductive effect and also it is far away from -COOH, which makes BrCH2CH2COOH weakest acid and hence, it has smallest dissociation constant.
Which one of the following processes is used for the manufacture of calcium?
Reduction of CaO with carbon
Reduction of CaO with hydrogen
Electrolysis of a mixture of anhydrous CaCl2 and KCl
Electrolysis of molten Ca(OH)2
Fe(OH)3 can be separated from Al(OH)3 by the addition of
NaCl solution
dil. HCl solution
NaOH solution
NH4Cl and NH4OH
Select the incorrect statement among the following:
O3 is used as germicide for purification of air
In O3, O-O bond length is identical with that of molecular oxygen
O3 molecule is angular in shape.
O3 is an oxidising agent
The brown complex obtained in the detection of nitrate radical is formulated as [Fe(H2O)5NO]SO4. What is the oxidation number of Fe in this complex?
+1
+2
+3
0
1 mole of methyl amine on reaction with nitrous acid gives at NTP
1.0 L of nitrogen
22.4 L of nitrogen
11.2 L of nitrogen
5.6 L of nitrogen