Amine that cannot be prepared by Gabriel phthalimide synthes

Subject

Chemistry

Class

NEET Class 12

Test Series

Take Zigya Full and Sectional Test Series. Time it out for real assessment and get your results instantly.

Test Yourself

Practice and master your preparation for a specific topic or chapter. Check you scores at the end of the test.
Advertisement

 Multiple Choice QuestionsMultiple Choice Questions

31.

In electrophilic aromatic substitution reaction, the nitro group is meta directing because it

  • decreases electron density at ortho and para positions

  • decreases electron density at meta position

  • increases electron density at meta position

  • ncreases electron density at ortho and para positions


32.

The best method for the conversion of an alcohol into an alkyl chloride is by treating the alcohol with

  • PCl3

  • PCl5

  • SOCl2 in presence of pyridine

  • dry HCl in the presence of anhydrous ZnCl2


33.

The compound which is not formed during the dry distillation of a mixture of calcium formate and calcium acetate is

  • methanal

  • propanal

  • propanone

  • ethanal


34.

The compound which forms acetaldehyde when heated with dilute NaOH, is

  • 1,1-dichloroethane

  • 1,1,1-trichloroethane

  • 1-chloroethane

  • 1,2-dichloroethane


Advertisement
35.

The condensation polymer among the following is

  • rubber

  • protein

  • PVC

  • polyethene


36.

In which of the following, NH3 is not used?

  • Tollen's reagent

  • Nessler's reagent

  • Group reagent for the analysis of IV group basic radicals

  • Group reagent for the analysis of III group basic radicals


Advertisement

37.

Amine that cannot be prepared by Gabriel phthalimide synthesis is

  • aniline

  • benzylamine

  • methylamine

  • iso-butylamine


A.

aniline

Only aliphatic primary amines can be prepared by Gabriel synthesis. Aniline cannot be prepared by this method because aryl halides (C6H5Cl or C6H5Br) do not undergo nucleophilic substitution with potassium phthalimide under ordinary conditions to give N-phenyl phthalimide (i.e., cleavage of C-X bond in haloarenes is quite difficult).

RX = aliphatic halide


Advertisement
38.

Lactose is made of

  • α-D-glucose only

  • α-D-glucose and β-D-glucose

  • α-D-galactose and β-D-glucose

  • β-D-galactose and β-D-glucose


Advertisement
39.

Cetyltrimethyl ammonium bromide is a popular

  • anionic detergent

  • cationic detergent

  • non-ionic detergent

  • sweetener


40.

The dispersed phase and dispersion medium in soap lather are respectively

  • gas and liquid

  • liquid and gas

  • solid and gas

  • solid and liquid


Advertisement