In BF3, the B - F bond length is 1.30Å, when BF3 is allowed to be treated with Me3N, it forms an adduct, Me3N BF3, the bond length of B - F in the adduct is
greater than 1.30 Å
smaller than 1.30 Å
equal to 1.30 Å
none of these
A.
greater than 1.30 Å
In BF3, there is back bonding in between fluorine and boron due to presence of p-orbital in boron. Back bonding imparts double bond characteristics.
As BF, forms adduct the back bonding is no longer present and thus double bond characteristic disappears. Hence, bond becomes a bit longer than earlier (1.30 Å).
A particle is moving 3 times faster than the speed of electron. If the ratio of wavelength of particle and electron is 1.8 x 10-4 then particle is
neutron
- particle
deuteron
tritium
Which thermodynamic parameter is not a state function?
q at constant pressure
q at constant volume
W at adiabatic
W at isothermal
Assertion : Bond dissociation energy is F2 > Cl2.
Reason : Cl2 has more electronic repulsion than F2.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.