The charge/size ratio of a cation determines its polarising power

Subject

Chemistry

Class

NEET Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

1.

For preparing 3.00 L of 1M NaOH by mixing portions of two stock solutions (A and B) of 2.50 M NaOH and 0.40 M NaOH respectively. Find out the amount of B stock solution (in L) added.

  • 8.57 L

  • 2.14 L

  • 1.28 L

  • 7.51 L


2.

The Vividh Bharti Station of All India Radio, Delhi, broadcasts on a frequency of 1,368 kHz (Kilohertz). Calculate the wavelength (λ) of the electromagnetic radiation emitted by transmitter. Which part of the electromagnetic spectrum does it belong to?

  • 319.4 m and X-rays

  • 319.4 m and radiowave

  • 219.3 m and microwave

  • 219.3 m and radiowave


3.

In an atom, an electron is moving with a speed of 600 m/s with an accuracy of 0.005%. Certainty with which the position of the electron can be located is

(Given, h= 6.6 x 10-34 kg m2 s-1, mass of electron em = 9.1 x 10-31 kg)

  • 215 x 10-3 m

  • 2.78 x 10-3 m

  • 1.92 x 10-3 m

  • 3.24 x 10-3 m


4.

What would be the heat released when an aqueous solution containing 0.5 mole of HNOis mixed with 0.3 mole of OH-?  (enthalpy of neutralisation is- 57.1 kJ)

  • 28.5 kJ

  • 17.1 kJ

  • 45.7 kJ

  • 1.7 kJ


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5.

The number average molar mass and mass average molar mass of a polymer are respectively 30,000 and 40,000. The
polydispersity index (PDI) of the polymer is 

  • -1

  • 0

  • > 1

  • < 1


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6.

The charge/size ratio of a cation determines its polarising power. Which one of the following sequences represents the increasing order of the polarising power of the cationic species, K+, Ca2+, Mg2+, Be2+?

  • K< Ca2+ < Mg2+ < Be2+

  • Be2+ < K2+ < Ca2+ < Mg2+

  • Mg2+< Be2+ < K+ < Ca2+

  • Ca2+ < Mg2+ < Be+ < K+


A.

K< Ca2+ < Mg2+ < Be2+

High charge and small size of the cations increases polarisation. As the size of the given cations decreases as

K> Ca2+ > Mg2+ > Be2+

Thus, polarising power increases as

K+ < Ca2+ < Mg2+ < Be2+


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7.

In an amino acid, the carboxyl group ionises at pKa = 2.34 and ammonium ion at pKa2 = 9.60. The isoelectric point of the amino acid is at pH

  • 4.32

  • 3.34

  • 9.46

  • 5.97


8.

0.40 g of helium in a bulb at a temperature of T K had a pressure of p atm. When the bulb was immersed in water bath at temperature 50 K more than the first one, 0.08 g of gas had to be removed to restore the original pressure. T is

  • 500 K

  • 400 K

  • 600 K

  • 200 K


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9.

What percentage of β-D-(+-glucopyranose is found at equilibrium in the aqueous solution?

  • 64%

  • 36%

  • 100%

  • 50%


10.

Which of the following is correctly arranged in order of increasing weight?

  • 0.0105 equivalent of H2CO2 ·2H2O < 0.625 g of Fe < 0.006 g atom of Ag <6.0 x 1021 atoms of Zn

  • 0.625 g of Fe < 0.0105 equivalent of H2C2O4 ·2H2O < 6.0 x 1021 atoms of Zn < 0.006 g atom of Ag 

  • 0.625 g of Fe < 6.0 x 1021 atoms of Zn < 0.006 g atom of Ag < 0.0105 equivalent of H2C2O4 ·2H2O

  • 0.0105 equivalent of H2C2O4. 2H2O < 0.006 g atom of Ag <6.0 x 1021 atoms of Zn < 0.625 g of Fe


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