The compounds (i) 2-Butene and (iv) 3, 4-Dimethyl-3-hexene would show geometrical isomerism. In both the cases, the two atoms or groups attached to the double bonded carbon atoms are different.
(i) But -2- ene (CH3 - CH = CH - CH3) exhibits geometrical isomerism.
(iv) 3, 4-Dimethylhex-3-ene: