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 Multiple Choice QuestionsMultiple Choice Questions

201.

In the reaction :

H2 + I2  2HI

In a 2 litre flask 0.4 moles of each H2 and I2 are taken .At equilibrium 0.5 moles of HI are formed .What will be the value of equilibrium constant ,Kc ?

  • 20.2

  • 25.4

  • 0.284

  • 11.11


202.

40 mL of 0.1 M ammonia solution is mixed with 20 mL. of 0.1 M HCl. What is the pH of the mixture? (pKb, of ammonia solution is 4.74)

  • 4.74

  • 2.26

  • 9.26

  • 5.00


203.

KI and CuSO4 solution when mixed , give :

  • CuI2 + K2SO4

  • Cu2I2 + K2SO4

  • K2SO+ Cu2I2 + I2

  • K2SO+ CuI2 + I2


204.

Which of the following is a Lewis base ?

  • NaOH

  • NH3

  • BCl3

  • All of these


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205.

For a phase change

H2O(l)   0°C, 1 bar  H2O(s)

  • G = 0

  • H = 0

  • S =0

  • U = 0


A.

G = 0

G°=-RTlnK  [G°= standard free energy change, K = equilibrium constant]

If a substance is in equilibrium between two phases at constant temperature and pressure, its chemical potential must have the same value in both the phases. Therefore G°=0.


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206.

F2 formed by reacting K2MnF6 with

  • SbF5

  • MnF3

  • KSbF6

  • MnF4


207.

Which among the following is the strongest acid ?

  • HF

  • HCl

  • HBr

  • HI


208.

When 10 mL of 0.1 M acetic acid (pK= 5.0) is titrated against 10 ml of 0.1 M ammonia solution (pK= 5.0), the equivalence point occurs at pH

  • 5.0

  • 6.0

  • 7.0

  • 9.0


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209.

For reaction, 2NOCl (g) 2NO (g) + Cl2 (g), Kc at 427°C is 3 × 10-6 L mol-1. The value of Kp is nearly

  • 7.50 × 10-5

  • 2.50 × 10-5

  • 2.50 × 10-4

  • 1.75 × 10-4


210.

For the chemical equilibrium,

CaCO3(s) CaO(s) + CO2(g)

Hr° can be determined from which one of the following plots?


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