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 Multiple Choice QuestionsMultiple Choice Questions

111.

In the compound HCC-C(CH3)=CH2 the hybridisation of C-2 and C-3 carbons are respectively

  • sp3 and sp3

  • sp2 and sp3

  • sp2 and sp

  • sp3 and sp


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112.

Which one of the following formulae does not represent an organic compound ?

  • C4H10O4

  • C4H6O4

  • C4H7ClO4

  • C4H9O4


D.

C4H9O4

C4H10O4 is CnH2n+2 type compound, ie with unsaturation factor 0, C4H8O4 and C4H7ClO4 are CnH2n (unsaturated) type compound, ie, have unsaturation factor 1 while C4H9O4 is CnH2n+1 type compound with unsaturation factor 0.5. Hence, C4H9O4 does not represent an organic compound.

            


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113.

C6H5NO2 Sn/ HCl C6H5X

'X' is identified as:

  • NO

  • -NH2

  • NHOH

  • None of these


114.

The test for unsaturation is confirmed by the decolourisation of which of the following ?

  • Iodine water

  • CusO4 solution

  • Bromine water

  • All of these


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115.

Catalyst used in dimerisation of acetylene to prepare chloroprene is

  • HgSO4 + H2SO4

  • Cu2Cl2

  • Cu2Cl2 + NH4Cl

  • Cu2Cl2 + NH4OH


116.

The dehydration of butan-1-ol gives

  • 1-butene as the main product

  • 2-butene as the main product

  • equal amounts of 1-butene and 2-butene

  • 2-methyl propene


117.

Cetane is a compound which has very good ignition property. Chemically it is

  • CH3(CH2)14CH3

  • (CH3)3C(CH2)11CH3

  • C17H34

  • None of the above


118.

The electrophile involved in the nitration of benzene is :

  • NO2

  • NO2+

  • NO

  • NO2-


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119.

Which of the following is most reactive towards electrophilic nitration ?

  • Toluene

  • Benzene

  • Benzoic acid

  • Nitrobenzene


120.

The most suitable reagent for the following conversion, is :

   

  • H2, Pd/C, quinoline

  • Zn/HCl

  • Hg2+/H+, H2O

  • Na/liquid NH3


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