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 Multiple Choice QuestionsMultiple Choice Questions

81.

A unit cell of sodium chloride has four formula units. The edge length of the unit cell is 0.564 nm. What is the density of sodium chloride?

  • 1.2 g/cm3

  • 2.165g/cm3

  • 3.64 g/cm3

  • 4.56 g/cm3


82.

The vapour pressure of pure benzene at a certain temperature is 0.850 bar. A non-volatile, non-electrolyte solid weighing 0.5 g is added to 39.0 g of benzene (molar mass 78 g/mol). The vapour pressure of the solution then is 0.845 bar. What is the molecular mass of the solid substance?

  • 58

  • 180

  • 170

  • 145


83.

2.0 molar solution is obtained, when 0.5 mole solute is dissolved in :

  • 250 ml solvent

  • 250 g solvent

  • 250 ml solution

  • 1000 ml solvent


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84.

What will be the normality of a solution, containing 4.9 g. H3PO4 dissolved in 500 ml water ?

  • 0.3

  • 1.0

  • 3.0

  • 0.1


A.

0.3

Given that, volume = 500 mL = 0.5 litre

weight of solute (w) = 4.9 g

equivalent weight of

H3PO4molecular weightbasicity

3 × 1 + 31 + 4 × 163 = 983

Hence, normality of solution (N)

wequivalent weight x volume

4.9983×0.5 = 0.3N


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85.

Phenolphthalein is not suitable for the titration of :

  • NaOH vs (COOH)2

  • KOH vs H2SO4

  • K2CO3 vs HCl

  • none of the above


86.

36 g water and 828 g ethyl alcohol form an ideal solution. The mole fraction of water in it, is :

  • 1.0

  • 0.7

  • 0.4

  • 0.1


87.

The weight of one molecule of a compound C60H120 is :

  • 1.2 x 10-20 g

  • 5.025 x 1023 g

  • 1.4 x 10-21 g

  • 6.023 x 1023 g


88.

MnO42- (1 mole) in neutral aqueous medium is disproportionated to

  • 2/3 mole of MnO4- and 1/3 mole of MnO2

  • 1/3 mole of MnO4- and 2/3 mole of MnO2

  • 1/3 mole of Mn2O7 and 1/3 mole of MnO2

  • 2/3 mole of Mn2O7 and 1/3 mole of MnO2


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89.

Assertion : Effusion rate of oxygen is smaller than nitrogen.

Reason: Molar mass of nitrogen is smaller than oxygen.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


90.

How many litres of ammonia gas at S.T.P. would 1 be needed to prepare 100 ml of 2.5 M ammonium hydroxide solution?

  • 5.6 L

  • 0.056 L

  • 11.2 L

  • 0.56 L


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