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 Multiple Choice QuestionsMultiple Choice Questions

51.

Sugars are seperated by using the solvent BAW (n-butanol acetic acid -HO) and detected by spraying the plate with

  • aniline hydrogen phthalate solution

  • hydrogen peroxide solution

  • crystals of I2

  • cupric oxide


52.

Product 'Q' is

  • an amide

  • an amine

  • nitro compound

  • nitrile compound


53.

Clemmensen reduction of a ketone is carried out in the presence of which of the following?

  • Zn-Hg with HCl

  • LiAlH4

  • H2 and Pt as catalyst

  • Glycol with KOH


54.

Which of the following is not a resonating form of benzaldehyde?


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55.

Which one of the following does not undergo iodoform reaction?

  • Secondary butyl alcohol

  • Iso-propyl alcohol

  • Diethyl ketone

  • Ethyl alcohol


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56.

CH3COOH Br2/ P Y (ii) H3O+(i) KCN X

Here, X is

  • glycollic acid

  • α-hydroxy propionic acid

  • succinic acid

  • malonic acid


D.

malonic acid

In the above reaction, X represents malonic acid. The reaction can be completed as

CH3COOH Br2P BrCH2 - COOH KCN (alc) NC - CH2COOH H3O+ HOOC - CH2 - COOH (malonic acid)


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57.

In electrophilic aromatic substitution reaction, the nitro group is meta directing because it

  • decreases electron density at ortho and para positions

  • decreases electron density at meta position

  • increases electron density at meta position

  • ncreases electron density at ortho and para positions


58.

The compound which is not formed during the dry distillation of a mixture of calcium formate and calcium acetate is

  • methanal

  • propanal

  • propanone

  • ethanal


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59.

The compound which forms acetaldehyde when heated with dilute NaOH, is

  • 1,1-dichloroethane

  • 1,1,1-trichloroethane

  • 1-chloroethane

  • 1,2-dichloroethane


60.

Which of the following reagents converts both acetaldehyde and acetone to alkanes ?

  • Ni/H2

  • LiAlH4

  • I2/ NaOH

  • Zn-Hg/ conc. HCl


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