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 Multiple Choice QuestionsMultiple Choice Questions

81.

The product of reaction between chloroform and acetone is used as :

  • insecticide

  • analgesic

  • hypnotic

  • war gas


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82.

The product formed by the reaction between acetylene and HOCl :

  • ethylene chloride

  • vinyl chloride

  • dichloro acetaldehyde

  • ethyledene chloride


C.

dichloro acetaldehyde


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83.

R-X Reagent R-NO3 , for the completion of the reaction suitable reagent is :

  • NO2

  • NaNO2

  • AgNO2

  • NaNO2 + dil. HCl


84.

The use of CCl4 as fire extinguisher depends on the fact that :

  • it is an inorganic compound

  • it is an organic compound

  • its vapour is much heavier than air and non-combustible

  • it is a compound of chlorine


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85.

Tertiary alkyl halides are practically inert towards substitution by SN2 mechanism because of :

  • steric hindrance

  • inductive effect

  • instability

  • insolubility


86.

Chloroform , on exposing to air and sunlight produce :

  • chloropicrin

  • phosgene

  • carbon tetrachloride

  • benzene


87.

Which of the following does not give nitroalkane?

  • CH3-N(CH3)-CH3 KMnO4

  • C2H5alc. AgNO2

  • CH3 - CH3 Fuming HNO3

  • Both (a) and (b)


88.

Which of the following is true for an ideal solution?

  • H(mix) = 0

  • S(mix) = 0

  • G(mix) = 0

  • None of these


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89.

Boiling point of benzene is 353.23 K. When 1.8 g of non-volatile solute is dissolved in 90 g of benzene. Then boiling point is raised to 354.11 K. Given Kb (benzene) = 2.5 kg mol-1. The molecular mass of non-volatile substance is

  • 58 g mol-1

  • 120 g mol-1

  • 116 g mol-1

  • 60 g mol-1


90.

But-1-ene H3O(CH3COO)2?

The product in the above reaction is

  • CH3CH2CH2CH2OH

  • CH3CH2CH(OH)CH3

  • CH2=CH2CH(OH)-CH3

  • CH3-CH=C(OH)-CH3


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