SN2 mechanism is involed in the following substitution :
CH3-CH2-Cl + OH-
(CH3)2-C(Cl)-CH3-OH-
(CH3)2-C-Cl + OH-
CH3-CH2-(CH3)C(Cl)-CH3 + OH-
Arrange the hydra - acids of halogens in increasing order of acidity .
HF < HCl < HBr < HI
HI < HBr < HCl < HF
HF < HBr < HI <HCl
HF < HI < HBr < HCl
IUPAC name of
CH3CH2C(Br)=CH-Cl is :
2 - bromo - l - chloro butene - 1
1 - chloro - 2 - bromo - butene
3 - chloro - 2 - bromo butene - 2
none of these
Which of the following sequence of reactions (reagents) can be used for the conversion of C6H5CH2CH3 into C6H5CH=CH2?
SOCl2 ; H2O
SO2Cl2; alc. KOH
Cl/h; H2O
SOCl2 ; alc. KOH.
B.
SO2Cl2; alc. KOH
Which ofthe following compounds has the highest boiling point?
CH3CH2CH2Cl
CH3CH2CH2CH2Cl
CH3CH(CH3)CH2Cl
(CH3)3CCl
The correct increasing order of the reactivity of halides for SN 1 reaction is
CH3- CH2- X<(CH3)2CH= X <CH2= CH-CH2- X< PhCH2- X
(CH3)2CH-X <CH3-CH2- X < CH2= CH - CH2-X < PhCH2-X
PhCH2- X<(CH3)2CH=X<CH3-CH2-X<CH2= CH- CH2- X
CH2= CH - CH2- X < Ph- CH2- X <(CH3)2CH-X <CH3-CH2- X
The major product formed in the following reaction is
(CH3)2CH-CH2OCH3
CH3-CH(OCH3)-CH2CH3
CH3-C(CH3)=CH2
(CH3)2-C-OCH3- CH3
The major product obtained on treatment of CH3CH2CH(F)CH3 with CH3O/CH3OH is
CH3CH2CH(OCH3)CH3
CH3CH = CHCH3
CH3CH2CH = CH2
CH3CH2CH2CH2OCH3
CH3CO2C2H5 on reaction with sodium ethoxide in ethanol gives A, which on heating in the presence of acid gives B. Compound B is
CH3COCH2COOH
CH3COCH3
CH2=C(OC2H5)2