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 Multiple Choice QuestionsMultiple Choice Questions

21.

Which of the following oxide is amphoteric?

  • SnO2

  • CaO2

  • SiO2

  • SiO2

476 Views

22.

Strong reducing behaviour of H3PO4 is due to

  • the presence of one -OH group and two P-H bonds

  • high electron gain enthalpy of phosphorous 

  • the high oxidation state of phosphorus

  • the high oxidation state of phosphorus

1388 Views

23.

Oxidation states of P in H4P2O5, H4P2O6, H4P2O7, are respectively

  • +3, +5, +4

  • +5, +3, +4

  • +5, +4,+3

  • +5, +4,+3

2318 Views

24.

The correct order of increasing bond angles in 

  • Cl2O < ClO2 < ClO2-

  • ClO2 <Cl2O< ClO2-

  • Cl2O < ClO2- < ClO2

  • Cl2O < ClO2- < ClO2

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25.

Match (I) substances with List (II) processes employed in the manufacture of the substances and select the correct option.

List I

List II

A

Sulphuric acid

1

Haber’s process

B

Steel

2

Bessemer’s process

C

Sodium

3

Lablanc process

D

Ammonia

4

Contact process

  • A

    B

    C

    D

    1

    4 2

    3

  • A

    B

    C

    D

    1

    2

    3

    4

  • A

    B

    C

    D

    4

    3 2 1
  • A

    B

    C

    D

    4

    3 2 1
305 Views

26.

which of the following oxides is not expected to react with sodium hydroxide?

  • B2O3

  • CaO

  • SiO2

  • SiO2

1120 Views

27.

Among the following which is the strongest oxidising agent?

  • F2

  • Br2

  • I2

  • I2

473 Views

28.

The stability of +1 oxidation state increases in the sequence 

  • Al < Ga <In < Tl

  • Tl < In <Ga< Al

  • In < Tl < Ga < Al

  • In < Tl < Ga < Al

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29.

Which one of the following arrangement does not give the correct picture of the trends indicated against it?

  • F2 > Cl2 > Br2 > I2 : Oxidising power

  • F2 > Cl2 > Br2 > I2 : Electron gain enthalpy

  • F2 > Cl2 > Br2 > I2 : Bond dissociation energy

  • F2 > Cl2 > Br2 > I2 : Bond dissociation energy


C.

F2 > Cl2 > Br2 > I2 : Bond dissociation energy

Generally, bond dissociation energies decrease in a group. Bond dissociation energy also decreases with repulsion.

X-X Bond F-F Cl-Cl Br- Br I-I
Bond length (A) 1.42 1.99 2.28 2.67
Bond dissociation energy (kcal/mol) 38 57 45.5 35.6

In general, the bond dissociation energy decreases as the bond length increases, but the bond dissociation energy of F2 is less than that of Cl2. It is due to greater interelectronic repulsion between the lone pair of electrons on the two bonded fluorine atoms. Hence, the order of bond dissociation energy  is as:

Cl2 > Br2 > F2 > I2
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30.

Which one of the following ionic species has the greatest proton affinity to form stable compound? 

  • HS-

  • NH2-

  • F-

  • F-


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