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CBSE

Subject

Chemistry
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NEET Chemistry : Alcohols, Phenols and Ethers

Multiple Choice Questions

111.

Assertion : Ethers can be dried by using sodium wire.

Reason : Ethers do not react with sodium.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false



112.

Dehydration of glycerol produces :

  • propanone

  • allyl alcohol

  • glycol

  • acrolein



113.

Assertion: C2H5Br reacts with alcoholic solution of AgNO2 to form nitroethane as the major product.

Reason : NO2- is an ambidient ion.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false



114.

CH3OC2H5 and (CH3)3C-OCH3 are treated with hydroiodic acid. The fragments after reactions obtained are

  • CH3I + HOC2H5; (CH3)3C-I + HOCH3

  • CH3OH + C2H5I; (CH3)3Cl + HOCH3

  • CH3OH + C2H5; (CH3)3C-OH + CH3I

  • CH3I + HOC2H5; CH3I + (CH3)3C-OH



115.

In which of the following reactions carbon-carbon bond formation takes place ?

  • Cannizaro

  • Reimer - Tiemann

  • HVZ reaction

  • Schmidt reaction



116.

 Soda lime A ? Anisole

Reagent in second step should be :

  • CH3Cl

  • KOH + C2H5OH

  • KOH + C2H5SH

  • KOH + Cl2



117.

In Oppenauer's oxidation,

  • secondary alcohol is oxidised to carboxylic acid in acetone solvent using aluminium tertiary butoxide

  • secondary alcohol is oxidised to carboxylic acid without affecting the C=C or C=C bond by aluminium tertiary butoxide in acetone solvent

  • secondary alcohol is oxidised to ketone without affecting C=C or C=C bond by aluminium tertiary butoxide

  • secondary alcohol is oxidised to ketone by chromic acid - pyridine complex.



118.

Assertion : In fused state, calcium chloride cannot be used to dry alcohol or NH3.

Reason : CaCl2 is not a good dessicant.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.



119.

In solvents like DMSO, acetonitrile, F- ion of dissolved NaF is more reactive than in methyl alcohol becasue

  • CH3OH is more polar than DMSO and CH3CN

  • CH3OH is less polar than DMSO and CH3CN

  • unsolvated F- ion is DMSO or CH3CN acts more efficiently as nucleophile

  • -OH group is a better leaving group than F- ion



120.

Assertion : Esters which contain α-hydrogens undergo Claisen condensation.

Reason : LiAlH4 reduction of esters gives acids.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false



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