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CBSE

Subject

Chemistry
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NEET Chemistry : Aldehydes, Ketones and Carboxylic Acids

Multiple Choice Questions

1.

The reaction by which benzaldehyde cannot be prepared? 

  •  +CrO2Cl2 and CS2 followed by H3O+
  •  +H2 in presence of anhydrous AlCl3.
  •  +CO +HCl in presence of anhydrous AlCl3
  •  +CO +HCl in presence of anhydrous AlCl3


2.

The correct statement regarding a carbonyl compound with a hydrogen atom on its alpha -carbon, is

  • a carbonyl compound with a hydrogen atom on its alpha -carbon rapidly equilibrates with its corresponding enol and this process is known as aldehyde-ketone equilibration.

  • a carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this process is known as carbonylation

  • a carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this process is known as keto-enol tautomerism

  • a carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this process is known as keto-enol tautomerism



3.

Treatment of cyclopentanone 

methyl lithium gives which of the following species?

  • Cyclopentanonyl anion

  • Cyclopentanonyl cation

  • Cyclopentanonyl radical

  • Cyclopentanonyl biradical



4.

Predict the products in the given reaction,



5.

Given,


Which of the given compounds can exhibit tautomerism?

  • I and II

  • I and III

  • II and III

  • II and III



6.

An organic compound X having molecular formula C5H10O yields phenyl hydrazone and gives negative response to the iodoform test and tollen test. It produces n -pentane on reduction X could be

  • pentanal

  • 2-pentanone

  • 3-pentanone

  • 3-pentanone



7.

Which of the following reagents would distinguish cis-cyclopenta-1-,2-diol from the trans isomer?

  • Ozone

  • MnO2

  • Aluminium isopropoxide

  • Aluminium isopropoxide



8.

CH3CHO and C6H5CH2CHO can be distinguished chemically by

  • Benedict test

  • Iodoform test

  • Tollen's reagent test

  • Tollen's reagent test



9.

Which one is most reactive towards nucleophilic addition reaction?



10.

Which one will not show Cannizzaro reaction ?

  • Trimethyl acetaldehyde

  • Formaldehyde

  • Acetaldehyde

  • Benzaldehyde



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