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CBSE

Subject

Chemistry
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NEET Chemistry : Aldehydes, Ketones and Carboxylic Acids

Multiple Choice Questions

41.

Which of the following is crossed aldol product in the reaction?

CH3CHO + CH3CH2CHO 25°COH- 'P'



42.

Consider the following compounds

Cl3C - COOH Br3C - COOH I3C - COOH

         (I)                   (II)          (III)

The decreasing order of decarboxylation is

  • I > II > III

  • III > II > I

  • III > I > II

  • II > I > III



43.

Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of comparable molecular mass. It is due to their

  • Formation of intramolecular H-bonding

  • Formation of intermolecular H-bonding

  • Formation of intermolecular H-bonding

  • More extensive association of carboxylic acid via Vander Waals force of attraction



44.

Iso-propyl chloride + A  2-ethoxy propane + NaCl

The compound (A) is

  • C2H5Cl

  • C2H5ONa

  • CH2N2

  • CH3ONa



45.

The product of acid hydrolysis of (P) and (Q) can be distinguished by

  • Lucas reagent

  • 2,4-DNP

  • Fehling's solution

  • NaHSO3



46.

Consider the reactions :

  • A-Methoxymethane, X-Ethanoic acid, Y-Acetate ion, Z-hydrazine

  • A-Methoxymethane, X-Ethanol, Y-Ethanoic acid, Z-Semicarbazide

  • A-Ethanal, X-Ethanol, Y-But-2-enal, Z-Semicarbazone

  • A-Ethanal, X-Ethanol, Y-But-2-enal, Z-Semicarbazone



47.

Clemmensen reaction of the ketone is carried out in the presence of

  • LiAlH4

  • Zn-Hg with HCl

  • glycol with KOH

  • H2 with Pt as a catalyst



48.

The IUPAC name of the compound

  • 3-keto-2-methylhex-4-enal

  • 5-formylhex-2-en-3-one

  • 5-methyl-4-oxohex-2-en-5-al

  • 5-methyl-4-oxohex-2-en-5-al



49.

Cannizzaro reaction is not shown by

  • CH3CHO

  • HCHO



50.

Compound A, C8H10O, is found to react with NaOI (produced by reacting Y with NaOH) and yields a yellow precipitate with characteristic smell. A and Y are respectively



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