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CBSE

Subject

Chemistry
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NEET Chemistry : Aldehydes, Ketones and Carboxylic Acids

Multiple Choice Questions

151.

Oxidation product of 1,2-cyclopentanediol with HIO4 gives

  • OHC-(CH2)3-CHO

  • COOH-CH-CH2-CH2-COOH

  • None of these



152.

Two moles of acetic acid are heated with P2O5 .The product formed is :

  • 2 moles of ethyl alcohol

  • formic anhydride

  • acetic anhydride

  • 2 moles of methyl cyanide



153.

The reaction , ROH + H2CNin the presence of HBF4 , gives the following product :

  • ROCH3

  • RCH2OH

  • ROHCN2N2

  • RCH2CH3



154.

CH3CHI2 KCN H2O ,  ?

Here the end product would be :

  • 2 - cyano propionic acid

  • ethane - l , 1 - dicarboxylic acid

  • 2 - methyl ethanoic acid

  • propionic acid



155.

Assertion : (CH3)3CCOC(CH3)3 and acetone can be distinguished by the reaction with NaHSO3.

Reason : HSO3- is the nucleophile in bisulphite addition.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.



156.

Which will give chiral molecule ?

  • CH3COCl LiAlH4

  • C2H5CHO H+/H2OCH3MgBr

  • (CH3)2CHC2H5 Cu

  • CH3-CH=C(CH3)2 Cl2



157.

If the enolate ion combines with carbonyl group of ester , we get :

  • aldol

  • α , β - unsaturated ester

  • β - keto aldehyde

  • acid



158.

Assertion : p-N,N-dimethylaminobenzaldehyde undergoes benzoin condensation.

Reason : The aldehydic (-CHO) group is meta directing.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false



159.

Identify the product Y in the sequence :

CH3CHO + CH3MgI Ether X H2O/H+ Y , is

  • CH3OH

  • CH3CH2OH

  • (CH3)2CHOH

  • (CH3)3COH



160.

Which of the following compounds will react with NaHCO3  solution to give sodium salt and carbon dioxide ?

  • Acetic acid

  • n - hexanol

  • Phenol

  • Both (b) and (c)



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