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CBSE

Subject

Chemistry
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NEET Chemistry : Aldehydes, Ketones and Carboxylic Acids

Multiple Choice Questions

31.

Which of the following represents the correct order of the acidity in the given compounds?

  • H3CCOOH > BrCH2COOH > ClCH2COOH > FCH2COOH

  • FCH2COOH > CH3COOH >BrCH2COOH > ClCH2COOH

  • BrCH2COOH > ClCH2COOH > FCH2COOH >CH3COOH

  • BrCH2COOH > ClCH2COOH > FCH2COOH >CH3COOH



32.

Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam and conc. HCl is Called:

  • Clemmensen reduction

  • Cope reduction

  • Dow reduction

  • Dow reduction



33.

A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin which on hydrolysis forms a racemic mixture of alpha-hydroxy acid. The carbonyl compound is:

  • acetaldehyde

  • acetone

  • diethyl ketone

  • diethyl ketone



34.

A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin which on hydrolysis forms a racemic mixture of alpha -hydroxy acid. The carbonyl compound is: 

  • CH3-CH2-CH2COCH3

  • (CH3)2C=O

  • CH3CH2CHO

  • CH3CH2CHO



35.

Self-condensation of two moles of ethyl acetate in presence of sodium ethoxide yields

  • ethyl butyrate

  • acetoacetic ester

  • methyl acetoacetate

  • methyl acetoacetate



36.

Which one of the following on treatment with 50% aqueous sodium hydroxide yields the corresponding alcohol and acid? 

  • C6H5CH2CHO

  • C6H5CHO

  • CH3CH2CH2CHO

  • CH3CH2CH2CHO



37.

Of the following, which is the product formed when cyclohexanone undergoes aldol condensation followed by heating?



38.

In a set of reactions, propionic acid yielded a compound D.

CH subscript 3 CH subscript 2 COOH space rightwards arrow with SOCl subscript 2 on top space straight B space rightwards arrow with NH subscript 3 on top space straight C space rightwards arrow from Br subscript 2 to KOH of space straight D
The structure of D would be:

  • CH3CH2CH2NH2

  • CH3CH2CONH2

  • CH3CH2NHCH3

  • CH3CH2NHCH3



39.

The product formed in aldol condensation is:

  • a beta-hydroxy acid

  • a beta -hydroxy aldehyde or ketone

  • an alpha -hydroxy aldehyde or ketone

  • an alpha -hydroxy aldehyde or ketone



40.

Which of the compounds with molecular formula C5H10 yields acetone on ozonolysis?

  • 2-methyl-2- butene

  • 3- methyl -1-butene

  • cyclopentane

  • cyclopentane



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