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CBSE

Subject

Chemistry
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NEET Chemistry : Chemical Kinetics

Multiple Choice Questions

11.

For the reaction, A+B → Products, it is observed that

1) On doubling the initial concentration of A only, the rate of reaction is also doubled and

2) On doubling the initial concentrations of both A and B , there is a change by a factor of 8 in the rate of the reaction.

The rate of this reaction is, given by

  • rate = k [A]2[B]

  • rate = k[A][B]2

  • rate = k[A]2[B]2

  • rate = k[A]2[B]2



12.

The unit of rate constant for a zero order reaction is 

  •  mol L-1 s-1

  • L mol-1 s-1

  • L2 mol-2 s-1

  • L2 mol-2 s-1



13.

The rate of the reaction,

2NO + Cl2 → 2NOCl is given by the rate equation, rate = k[NO]2[Cl2]

The value of the rate constant can be increased by

  • increasing the temperature

  • increasing the concentration of NO

  • increasing the concentration of the Cl2

  • increasing the concentration of the Cl2



14.

The rate of constant of the reaction A → B is  0.6 x 10-3 mole per second. If the concentration of A is 5 M then concentration of B after 20 min is 

  • 1.08 M

  • 3.60 M

  • 0.36 M

  • 0.36 M



15.

Half-life period of a first order reaction is 1386 s. The specific rate constant of the reaction is

  • 5.0 x 10-3s-1

  • 0.5 x 10-2 s-1

  • 0.5 x 10-3 s-1

  • 0.5 x 10-3 s-1



16.

For the reaction

straight N subscript 2 straight O subscript 5 left parenthesis straight g right parenthesis thin space rightwards arrow space 2 NO subscript 2 space left parenthesis straight g right parenthesis thin space plus space 1 half space straight O subscript 2 space left parenthesis straight g right parenthesis
the value of the rate of disappearance of N2O5 is given as 

  • 6.25 x 10-3 mol L-1s-1 and 6.25 x 10-3 mol L-1 s-1

  • 1.25 x 10-2 mol L-1s-1 and 6.25 x 10-3 mol L-1 s-1

  • 6.25 x 10-3 mol L-1s-1 and 3.125 x 10-3 mol L-1 s-1

  • 6.25 x 10-3 mol L-1s-1 and 3.125 x 10-3 mol L-1 s-1



17.

For an endothermic reaction, energy of activation is Ea and enthalpy of reaction is ΔH (both of these in kJ/mol). Minimum value of Ea will be

  • less than ΔH

  • equal to ΔH

  • more than ΔH

  • more than ΔH



18.

During the kinetic study of the reaction, 2A + B --> C+ D,  following results were obtained 


 

[A]/mol L-

[B]/ mol L-

Initial rate of formation of D/ mol L- min-

I

0.1

0.1

6.0 x 10-3

II

0.3

0.2

7.2 x 10-2

III

0.3

0.4

2.88 x 10-1

IV

0.4

0.1

2.40 x10-2

 
based on the above data which one of the following is correct?
  • rate = k[A]2[B]

  • rate = k [A][B]

  • rate = k[A]2[B]2

  • rate = k[A]2[B]2



19.

The rate of reaction 2N2O3 → 4 NO2 + O2 can be written in three ways

fraction numerator negative straight d left square bracket straight N subscript 2 straight O subscript 5 right square bracket over denominator dt end fraction space equals space straight k space left square bracket straight N subscript 2 straight O subscript 5 right square bracket

fraction numerator straight d left square bracket NO subscript 2 superscript 7 right square bracket over denominator dt end fraction space equals space k apostrophe left square bracket N subscript 2 O subscript 5 right square bracket

fraction numerator straight d left square bracket straight O subscript 2 right square bracket over denominator dt end fraction space equals space straight k apostrophe apostrophe space left square bracket straight N subscript 2 straight O subscript 5 right square bracket

The relationship between k and k' and between k and k'' are 

  • k' = 2k ; k' = k

  • k' = 2k; k" = k/2

  • k' = 2k; k' = 2k

  • k' = 2k; k' = 2k



20.

The half -life of a substance in a certain enzyme catalysed reaction is 138 s. The time required for the concentration of the substance to fall from 1.28 mg L-1 is 

  • 414 s

  • 552 s 

  • 690 s

  • 690 s



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