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CBSE

Subject

Chemistry
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NEET Chemistry : Chemical Kinetics

Multiple Choice Questions

61.

The half life of a radioactive element is 40 days. Calculate the average life

  • 5.76 days

  • 57.6 days

  • 646 days

  • 4.56 days



62.

A first order reaction, which is 30% complete in 30 minutes has a half-life period of

  • 102.2 min

  • 58.2 min

  • 24.2 min

  • 120.2 min



63.

One of the hazardous explosion is the generation of 90Sr and its subsequent incorporation in bones. This nuclide has a half life of 28.1 years. Suppose one microgram was absorbed by a new born child. How much 90Sr will remain in his bones after 20 years?

  • 0.061 µg

  • 0.080µg

  • 0.050µg

  • 0.030µg



64.

For a reaction, the half-life is independent of initial concentration. What is the order of that reaction?

  • Zero

  • One

  • Two

  • Three



65.

How will the rate of reaction , 2NO + O2  2NO2 change, if the volume of the reaction vessel is doubled?

  • It will diminish to 1/4 of the initial value

  • It will diminish to 1/8 of the initial value

  • It will grow four times

  • It will grow eight times



66.

There is a steam of neutrons with a kinetic energy of 0.0327 eV. If the half life of neutrons s 700 s, what fraction of neutrons will decay before they travel a distance of 10 km?

  • 0.001

  • 0.004

  • 0.006

  • 0.009



67.

The chemical reaction, 2O3  3Oproceeds as follows:

Step 1 : O3  O2 + O  ...(fast)

Step 2 : O + O3 2O2 ...(slow)

The rate law expression should be

  • r = k' [O3][O2]

  • r = k'[O3]2[O2]-1

  • r = k'[O3]2

  • unpredictable



68.

Consider the following statements :
I. Increase in concentration of reactant increases the rate of a zero order reaction
II. Rate constant k is equal to collision frequency A , if Ea =0

III. Rate constant k is equal to collision
frequency A , if Ea = ∞
IV. ln k vs T is a straight line
V. ln k vs 1/T is a straight line

Correct statements are :

  • I and IV

  • II and V

  • III and IV

  • II and III



69.

The rate of reaction , 2NO + Cl2  2NOCl becomes double when the concentration of Cl2 is doubled. However, when the concentration of both the reactants is doubled the rate becomes eight times. What is order of the reaction?

  • First

  • Second

  • Third

  • Zero



70.

For a chemical reaction A  B, the rate of the reaction is 2x10-3 mol dm-3 s-1 , when the initial concentration is 0.05 mol dm-3 . The rate of the same reaction is 1.6 x 10-2 mol dm-3 s-1 , when the initial concentration is 0.1 mol dm-3 .The order of the reaction is :

  • 2

  • 0

  • 3

  • 1



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