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CBSE

Subject

Chemistry
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NEET Chemistry : Chemical Kinetics

Multiple Choice Questions

71.

For the reaction A(g)B( g)+ C(g), the rate constant is given as (Pi is initial pressure and Pt is pressure at time t)

  • k=2.303tlogPiPt 

  • k=2.303tlogPi(2Pi-Pt)

  • k=2.303tlog2Pi-PtPi

  • k=2.303tlogPi -Pt2Pi



72.

The activation energy for most of the reactions is approximately 50 kJ mol-1 .The value of temperature coefficient for such reactions is :

  • > 2

  • > 3

  • < 1

  • > 4



73.

Which one of the following options is not correct for the decomposition reaction of NH3 ?

2NH3 (g) Pt catalyst1130 K , at high p N2 (g) + 3H2 (g)

  • Rate of reaction = rate constant

  • Further increase in pressure will change the rate of reaction

  • Rate of decomposition of NH3 will remain constant until NH3 disappears completely

  • Rate of reaction depends on concentration of NH3



74.

75% of a zero order reaction complete in 4 h 87.5% of the same reaction completes in

  • 6h

  • 12h

  • 8h

  • 2h



75.

For the reaction , aA + bB  cC , if -3d[A]dT = -3d[B]dt = +1.5d[C]dt then a , b , c respectively are :

  • 1 , 3 , 2

  • 1 , 2 , 3

  • 3 , 2 , 1

  • 3 , 1 , 2



76.

The role of a catalyst is to change :

  • enthalpy of reaction

  • equilibrium constant

  • activation energy of reaction

  • Gibbs energy of reaction



77.

For reaction aA xP, when [A] = 2.2 mM, the rate was found to be 2.4 mM s-1. On reducing concentration of A to half, the rate changes to 0.6 mM s-1.The order of reaction with respect to A is

  • 1.5

  • 2.0

  • 2.5

  • 3.0



78.

If the rate of reaction , A  B doubles on increasing the concentration of A by 4 times , the order of the reaction is :

  • 2

  • 1

  • 0.5

  • 4



79.

For a first order reaction at 27°C , the ratio of time required for 75% completion to 25% completion of reaction is :

  • log 43

  • log 34

  • log 4log 4/3

  • log 4/3log 4



80.

The plot of a concentration of the reactant versus time for a reaction is a straight line with a negative slope. The reaction follows a

  • first order rate equation

  • zero order rate equation

  • second order reaction

  • third order rate equation



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