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CBSE

Subject

Chemistry
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NEET Chemistry : Electrochemistry

Multiple Choice Questions

101.

Assertion : Magnesium is extracted by the electrolysis of fused mixture of MgCl2, NaCl and CaCl2.

Reason : Calcium chloride acts as a reducing agent.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.



102.

Assertion : Reduction potential of Mn (+3 to +2) is more positive than Fe (+3 to +2).

Reason: Ionisation potential of Mn is more than that of Fe.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.



103.

Calculate HOAC using appropriate molar conductances of the electrolytes listed above at infinite dilution in H2O at 25°C.

Electrolyte  KCl  KNO3  HCL  NaOAc  NaCl
  S cm2mol-1  149.9  145.0  426.2  91.0  126.5

  • 517.2

  • 552.7

  • 390.7

  • 217.5



104.

Assertion : Zinc displaces copper from copper sulphate solution.

Reason : The E°of zinc is= 0.76 V and that of copper is + 0.34 V.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.



105.

Which one of the following condition will increase the voltage of the cell represented by the equation ?

Cu (s) + 2Ag+ (aq)  Cu2+ (aq) + 2Ag (s)

  • Increase in the dimension of Cu electrode

  • Increase in the dimension of Ag electrode

  • Increase in the concentration of Cu2+ ion

  • Increase in the concentration of Ag+ ions



106.

When a quantity of electricity is passed through CusO4 solution , 0.16 g of copper gets deposited .If the same quantity of electricity is passed through acidulated water , then the volume of H2 liberated at STP will be :

[Given : atomic weight of Cu = 64]

  • 10 cm3

  • 56 cm3

  • 604 cm3

  • 8.0 cm3



107.

Which of the following electrolyte will have maximum flocculation value for Fe(OH)3 sol ?

  • NaCl

  • Na2S

  • (NH4)3PO4

  • K2SO4



108.

The standard half-cell reduction potential for Ag+| Ag is 0.7991 V at 25°C. Given the experimental value Ksp= 1.56 x 10-10 for AgCl, calculate the standard half-cell reduction potential for the Ag | AgCl electrode.

  • 0.2192V

  • -0.2192V

  • -1.2192 V

  • 1.2192 V



109.

Which of the following does not conduct electricity ?

  • Fused NaCl

  • Solid NaCl

  • Brine solution

  • Copper



110.

For the electrochemical cell, M | M+ || X- | X, E°(M+| M) = 0.44 V and E°(X | X-) = 0.33 V. From this data one can deduce that

  • M + X- M- + X- is the spontateous reaction.

  • M+ + X- M + X is the spontaneous reaction.

  • Ecell = 0.77 V

  • Ecell = -0.77V



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