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CBSE

Subject

Chemistry
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NEET Chemistry : Equilibrium

Multiple Choice Questions

11.

Give that the equilibrium constant for the reaction,

2SO2 (g) + O2 (g)  ⇌ 2SO3 (g)

has a value of 278 at a particular temperature. What is the value of the equilibrium constant for the following reaction t the same temperature?

SO3 (g)  ⇌ SO2 (g) +1/2 O2 (g)

  • 1.8 x 10-3

  • 3.6 x 10-3

  • 6.0 x 10-2

  • 6.0 x 10-2



12.

A buffer solution is prepared in which the concentration of NH3 is 0.30 M and the concentration of NH4 is 0.20 M. If the equilibrium constant, Kb for NH3 equals 1.8 x 10-5, what is the pH of this solution?

log ( 2.7 = 0.43)

  • 9.43

  • 11.72

  • 8.73

  • 9.08



13.

Buffer solutions have constant acidity and alkalinity because

  • these give unionised acid or base on reaction with added acid or alkali

  • acids and alkalies in these solutions are shielded from attack by other ions.

  • they have a large excess of H+ or OH- ions

  • they have a large excess of H+ or OH- ions



14.

Which one of the following pairs of the solution is not an acidic buffer?

  • HClO4 and NaClO4

  • CH3COOH and CH3COONa

  • H2CO3 and Na2PO4

  • H2CO3 and Na2PO4



15.

The value of ΔH for the reaction

X2 (g) + 4Y2 (g) ⇌ 2XY4 (g) is less than zero. Formation of XY4 (g) will be favoured at

  • Low pressure and low temperature

  • high temperature and low pressure

  • high pressure and low temperature

  • high pressure and low temperature



16.

pH of a saturated solution of Ba(OH)2 is 12. The value of solubility product Ksp of Ba(OH)2 is

  • 3.3 x 10-7

  • 5.0 x 10-7

  • 4.0 x 10-6

  • 4.0 x 10-6



17.

What is the pH of the resulting solution when equal volumes of 0.1 M NaOH and 0.01 M HCl are mixed?

  • 12.65

  • 2.0

  • 7.0

  • 7.0



18.

Given the reaction between two gases represented by A2 and B2 to give the compound AB (g).
A2(g) +B2 (g)  ⇌ 2AB (g)
At equilibrium the concentration
of A2 = 3.0 x 10-3 M
of B2 = 4.2 x 10-3 M
of AB = 2.8 x 10-3 M

If the reaction takes place in a sealed vessel at 527oC, then the value of Kc will be

  • 2.0

  • 1.9

  • 0.62

  • 0.62



19.

For the reaction N2 (g) + O2 (g) ⇌  2NO (g), the equilibrium constant is K1. The equilibrium constant is K2 for the reaction 2NO (g) + O2(g) ⇌ 2NO2 (g). What is K for the reaction NO subscript 2 space left parenthesis straight g right parenthesis space rightwards harpoon over leftwards harpoon 1 half straight N subscript 2 space left parenthesis straight g right parenthesis space plus straight O subscript 2 space left parenthesis straight g right parenthesis ? space space

  • 1/(4K1K2)

  • [1/K1K2]1/2

  • 1/(K1K2)

  • 1/(K1K2)



20.

Equimolar solutions of the following substances were prepared separately, which one of these will record the highest pH value?

  • BaCl2

  • AlCl3

  • LiCl

  • LiCl



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