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CBSE

Subject

Chemistry
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NEET Chemistry : Haloalkanes and Haloarenes

Multiple Choice Questions

11.

In the following reactions,



the major (A) and (C) are respectively



12.

In the reaction with HCl, an alkene reacts in accordance with the markownikoff's rule, to give a product 1-chloro -1- methylcyclohexane. The possible alkane is 

  • (a) and (b)

  • (a) and (b)



13.

In an SN1 reaction on chiral centres, there is 

  • 100% racemisation

  • inversion more than retention leading to partial racemization

  • 100% retention

  • 100% retention



14.

The order of reactivity of phenyl magnesium bromide (phMgBr) with the following compounds.


  • III > II> I

  • II > I > III

  • I > III > II

  • I > III > II



15.

Consider the reactions


space left parenthesis straight i right parenthesis space left parenthesis CH subscript 3 right parenthesis subscript 2 CH minus space CH subscript 2 space minus space CH subscript 2 space Br space rightwards arrow with straight C subscript 2 straight O subscript 5 OH on top space left parenthesis CH subscript 3 right parenthesis subscript 2 CHCH subscript 2 OC subscript 2 straight H subscript 5 space plus space Br to the power of minus

left parenthesis ii right parenthesis space left parenthesis CH subscript 3 right parenthesis subscript 2 CHCH subscript 2 Br rightwards arrow with straight C subscript 2 straight H subscript 5 straight O to the power of minus on top space left parenthesis CH subscript 3 right parenthesis subscript 2 CHCH subscript 2 OC subscript 2 straight H subscript 5 space plus Br to the power of minus

The mechanisms of reactions (i) and (ii) are respectively

  • SN1 and SN2

  • SN1 and SN1

  • SN2 and SN2

  • SN2 and SN2



16.

In the following sequence of reactions,

CH subscript 3 minus Br space rightwards arrow with KCN on top space straight A rightwards arrow with straight H subscript 3 straight O to the power of plus on top straight B space rightwards arrow from ether to LiAlH subscript 4 of space straight C
the end product is (C) is

  • acetone

  • methane

  • acetaldehyde

  • acetaldehyde



17.

Which of the following reaction (s) can be used for the preparation of alkyl halides?


straight I. space CH subscript 3 CH subscript 2 OH space plus space HCl space rightwards arrow with Anh. ZnCl subscript 2 on top

II. space CH subscript 3 CH subscript 2 OH space plus space HCl space rightwards arrow

III. space left parenthesis CH subscript 3 right parenthesis subscript 3 COH space plus space HCl space rightwards arrow

IV. space left parenthesis CH subscript 3 right parenthesis subscript 2 CHOH space plus space HCl space rightwards arrow with anh. space ZnCl subscript 2 on top

  • I, III and IV

  • I and II

  • Only IV

  • Only IV



18.

Which one is most reactive towards SN1 reaction?

  • C6H5CH(C6H5)Br

  • C6H5CH(CH3)Br

  • C6H5C(CH3)(C6H5)Br

  • C6H5C(CH3)(C6H5)Br



19.

2,3 -dimethyl - 2- butene can be prepared by heating which of the following compounds with a strong acid?

  • (CH3)2CH-CH(CH)3-CH=CH2

  • (CH3)3C-CH=CH2

  • (CH3)2C =CH-CH2-CH3

  • (CH3)2C =CH-CH2-CH3



20.

The IUPAC name of the following compound

  • trans - 2- chloro - 3 - iodo - 2 - pentene

  • cis - 3- iodo - 4-  chloro - 3- pentene

  • trans - 3- iodo - 4- chloro - 3- pentene

  • trans - 3- iodo - 4- chloro - 3- pentene



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