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CBSE

Subject

Chemistry
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NEET Chemistry : Haloalkanes and Haloarenes

Multiple Choice Questions

141.

The ease of dehydrohalogenation of alkyl halide with alcoholic KOH is:

  • 3° < 2° < 1°

  • 3° > 2° > 1 °

  • 3° < 2° > 1°

  • 3° > 2° < 1 °



142.

Under identical conditions, the SN1 reaction will occur most efficiently with:

  • tert-butyl chloride

  • 1-chlorobutane

  • 2-methyl-1-chloropropane

  • 2-chlorobutane



143.

Best reagent for nuclear iodination of aromatic compounds is

  • KI/ CH3COCH3

  • I2/CH3CN

  • KI/ CH3COOH

  • I2 / HNO3



144.

The correct statement regarding the following compounds is

  • all three compounds are chiral

  • only I and II are chiral

  • I and III are diastereomers

  • only I and III are chiral



145.

In a mixture, two enantiomers are found to be present in 85% and 15% respectively. The enantiomeric excess (ee) is

  • 85%

  • 15%

  • 70%

  • 60%



146.

Boiling water reacts with C6H5N2+Cl- to give

  • aniline

  • benzylamine

  • phenol

  • benzaldehyde



147.

The IUPAC name of the compound having the formula CCl3CH2CHO is

  • 2, 2, 2-trichloropropanal

  • 1,1, 1-trichloropropanal

  • 3, 3, 3-trichloropropanal

  • 1, 2, 1-dichloromethanal



148.

Identify the correct method for the synthesis of the compound shown below from the following alternatives.



149.

Which one of the following methods are used to prepare Me3COEt with good yield?

  • Mixing EtONa with Me2CCl

  • Mixing Me2CONa with EtCl

  • Heating a mixture of (1:1) EtOH and Me2COH in the presence of conc. H2SO4

  • Treatment of Me3COH with EtMgI



150.

Identify the method by which Me3CCO2H can be prepared:

  • Treating 1 mole of MeCOMe with 2 moles of MeMgl

  • Treating 1 mole of MeCO3Me with 3 moles of MeMgI

  • Treating 1 mole of MeCHO with 3 moles of MeMgl

  • Treating 1 mole of dry ice with 1 mol of MeCMgI



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