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CBSE

Subject

Chemistry
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NEET Chemistry : Organic Chemistry – Some Basic Principles and Techniques

Multiple Choice Questions

91.

Assertion : Thiophene present in commercial benzene as an impurity can be removed by shaking the mixture with cold concentrated H2SO4.

Reason : Thiophene is a heterocyclic aromatic compound.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.



92.

Which of the following compounds is aromatic in nature?



93.

Which ofthe following complexes exists as pair of enantiomers ?

  • trans-[Co(en)2Cl2]+

  • [Co(NH3)2Cl2]+

  • [Co{P(C2H5)3}2ClBr]

  • [Cr(en)3]3+



94.

What is the correct order of basicity among the following compounds ?

  • II > I > III > IV

  • I > II > III > IV

  • III > I > II > IV

  • I > III > II > IV



95.

Which of the following species is not aromatic?

  • Benzene

  • Cyclooctatetraenyl dianion

  • Tropylium ion

  • Cyclopentadienyl cation



96.

Select the correct statement.

  • Geometrical isomer may differ in dipole moment and visible/UV spectra.

  • Complexes of the type [Ma3b3] can also have facial (fac) and meridional (mer) isomer.

  • No optical isomer exists for the complex trans- [Co(en)2Cl2]+.

  • All of these.



97.

Ease of nucleophilic addition in the given compounds is

  • I > III > II

  • II > III > I

  • II > I > III

  • III > I > II



98.

Which one of the following is the most stable reactive intermediate?



99.

Which of the following is an electrophile?

  • CCl2

  • CH3-

  • H2O

  • NH3



100.

Arrange the following nucleophiles in the decreasing order of nucleophilicity :

(A) CH3COO-

(B) CH3O-

(C) CN-

(D) 

  • C, B, A, D

  • A, B, C, D

  • C, C, B, A

  • B, C, A, D



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